The DOI matches its Crossref record; 54 of the 54 references it cites were found in a registry or an index.
{Zn6} Cluster Based Metal–Organic Framework with Enhanced Room-Temperature Phosphorescence and Optoelectronic Performances
Abstract
Molecule-based solid-state materials with long lifetimes could enable longer migration distances for excitons, which are beneficial for vast applications in optoelectronic field. Herein, we report a hexanuclear zinc cluster based MOF exhibits highly enhanced phosphorescence about 2 orders of magnitude in comparison with the pristine phosphor ligand. The combination of both experimental and computational results suggest that the {Zn 6 } cluster is very important for adjusting molecular conformations, packing arrangement, and photophysical properties of the organic phosphor ligands within the MOF matrix. Optoelectronic measurements reveal that the MOF-modified electrode is catalytically active to hydrogen evolution under light irradiation in neutral solution. Thus, our study provide an effective way to achieve low-cost metal-based phosphorescence MOF, expanding its further optoelectronic applications.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
SHELXT – Integrated space-group and crystal-structure determination
Sheldrick, G. M. (2015) · Acta Crystallographica Section A Foundations and Advances · doi:10.1107/s2053273314026370 · Cited by 29,831
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1992) · Physical Review B · doi:10.1103/physrevb.46.6671 · Cited by 22,269
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1993) · Physical Review B · doi:10.1103/physrevb.48.4978.2 · Cited by 17,144
From molecules to solids with the DMol3 approach
Delley, B. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1316015 · Cited by 11,026
An all-electron numerical method for solving the local density functional for polyatomic molecules
Delley, B. (1990) · The Journal of Chemical Physics · doi:10.1063/1.458452 · Cited by 10,536
Reticular synthesis and the design of new materials
Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003) · Nature · doi:10.1038/nature01650 · Cited by 9,101
Metal–organic frameworks: functional luminescent and photonic materials for sensing applications
Lustig, W. P., Mukherjee, S., Rudd, N. D., Desai, A. V., Li, J., & Ghosh, S. K. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00930a · Cited by 3,050
Stabilizing triplet excited states for ultralong organic phosphorescence
An, Z., Zheng, C., Tao, Y., Chen, R., Shi, H., Chen, T., Wang, Z., Li, H., Deng, R., Liu, X., et al. (2015) · Nature Materials · doi:10.1038/nmat4259 · Cited by 1,944
Activating efficient phosphorescence from purely organic materials by crystal design
Bolton, O., Lee, K., Kim, H.-J., Lin, K. Y., & Kim, J. (2011) · Nature Chemistry · doi:10.1038/nchem.984 · Cited by 1,662
Metadata
- Authors
- Zhao, Y., Yang, X.-G., Lu, X.-M., Yang, C.-D., Fan, N.-N., Yang, Z.-T., Wang, L.-Y., & Ma, L.-F.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-04-19
- Volume
- 58
- Issue
- 9
- Pages
- 6215-6221
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2938751887
- Cited by
- 253
- References
- 54
- FWCI
- 18.82
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: {Zn6} Cluster Based Metal–Organic Framework with Enhanced Room-Temperature Phosphorescence and Optoelectronic Performances. https://app.cochat.ai/papers/10.1021/acs.inorgchem.9b00450
- The paper
- Zhao, Y., Yang, X.-G., Lu, X.-M., Yang, C.-D., Fan, N.-N., Yang, Z.-T., Wang, L.-Y., & Ma, L.-F. (2019). {Zn6} Cluster Based Metal–Organic Framework with Enhanced Room-Temperature Phosphorescence and Optoelectronic Performances. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.9b00450
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
