The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Recognizing the Limited Applicability of Job Plots in Studying Host–Guest Interactions in Supramolecular Chemistry
Open accessAbstract
Continuous variation method, known as Job plot, is the most commonly applied method for the determination of stoichiometry of complex chemical entities for over 100 years. Although, the method was proven successful in the analysis of very stable metal-ligand complexes, we demonstrate that its use in supramolecular chemistry often provides false results. We support this statement with multiple simulations as well as cases studies of several real host-guest systems. We propose an alternative, general method relying on the analysis of residual distribution in titration data fitting. The latter method is more convenient compared to the Job plot and unlike it gives correct results in all real cases studied.
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Cites
Determining association constants from titration experiments in supramolecular chemistry
Thordarson, P. (2011) · Chem. Soc. Rev. · doi:10.1039/c0cs00062k · Cited by 2,419
Hynes, M. J. (1993) · Journal of the Chemical Society, Dalton Transactions · doi:10.1039/dt9930000311 · Cited by 840
A Practical Guide for the Determination of Binding Constants
Hirose, K. (2001) · Journal of inclusion phenomena and macrocyclic chemistry · doi:10.1023/a:1011117412693 · Cited by 605
Intuitive Biostatistics: A Nonmathematical Guide to Statistical Thinking
Motulsky, H. J. (2017) · Cited by 334
One-step synthesis of dipyrromethanes in water
SOBRAL, A. J. F. N., Rebanda, N. G. C. L., da Silva, M., Lampreia, S. H., Silva, M. R., Beja, A. M., Paixão, J. A., & Gonsalves, A. M. D. R. (2003) · Tetrahedron Letters · doi:10.1016/s0040-4039(03)00785-8 · Cited by 104
Chiral Recognition of Carboxylates by a Static Library of Thiourea Receptors with Amino Acid Arms
Ulatowski, F., & Jurczak, J. (2015) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.5b00403 · Cited by 48
Self-citation
Cited by
Detailed NMR investigation of cyclodextrin-perfluorinated surfactant interactions in aqueous media
Weiss-Errico, M. J., & O’Shea, K. E. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.01.017 · Cited by 77
Metadata
- Authors
- Ulatowski, F., Dąbrowa, K., Bałakier, T., & Jurczak, J.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-17
- Volume
- 81
- Issue
- 5
- Pages
- 1746-1756
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2265242384
- Cited by
- 375
- References
- 6
- FWCI
- 19.75
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- The paper
- Ulatowski, F., Dąbrowa, K., Bałakier, T., & Jurczak, J. (2016). Recognizing the Limited Applicability of Job Plots in Studying Host–Guest Interactions in Supramolecular Chemistry. The Journal of Organic Chemistry. https://doi.org/10.1021/acs.joc.5b02909
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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