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Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement

Tyagi, Pooja, Arveson, Sarah M., Tisdale, William A.·2015·The Journal of Physical Chemistry Letters

Abstract

We prepare colloidal nanoplatelets of methylammonium lead bromide (MAPbBr3) perovskite and compare the optical signatures of excitons in these two-dimensional systems to spherical perovskite nanocrystals and the corresponding bulk phase. We find that excitonic features that had previously been attributed to quantum confinement in MAPbBr3 nanocrystals are in fact a property of the bulk perovskite phase. Furthermore, we find that higher-energy absorption features originate from two-dimensional nanoplatelets, which are present in the nanocrystal reaction product. Upon further purification, we obtain colloidal nanoplatelets with predominantly single unit cell thickness and submicron lateral dimensions, which are stable in solution and exhibit a sharp excitonic absorption feature 0.5 eV blue-shifted from that of the three-dimensional bulk MAPbBr3 phase, representing a new addition to the growing family of colloidal two-dimensional nanostructures.

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Metadata

Authors
Tyagi, P., Arveson, S. M., & Tisdale, W. A.
Venue
The Journal of Physical Chemistry Letters
Published
2015-05-07
Volume
6
Issue
10
Pages
1911-1916
ISSN
1948-7185 (ISSN-L)
OpenAlex
W1447737051
Cited by
416
References
46
FWCI
28.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement. https://app.cochat.ai/papers/10.1021/acs.jpclett.5b00664
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Tyagi, P., Arveson, S. M., & Tisdale, W. A. (2015). Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.5b00664

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