The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Photoinduced Reversible Structural Transformations in Free-Standing CH3NH3PbI3 Perovskite Films
Open accessAbstract
In the pursuit to better understand the mechanisms of perovskite solar cells we performed Raman and photoluminescence measurements of free-standing CH3NH3PbI3 films, comparing dark with working conditions. The films, grown on a glass substrate and sealed by a thin glass coverslip, were measured subsequent to dark and white-light pretreatments. The extremely slow changes we observe in both the Raman and photoluminescence cannot be regarded as electronic processes, which are much faster. Thus, the most probable explanation is of slow photoinduced structural changes. The CH3NH3PbI3 transformation between the dark and the light structures is reversible, with faster rates for the changes under illumination. The results seem to clarify several common observations associated with solar cell mechanisms, like performance improvement under light soaking. More important is the call for solar-cell-related investigation of CH3NH3PbI3 to take the photoinduced structural changes into consideration when measuring and interpreting the results.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Deschler, F., Price, M., Pathak, S., Klintberg, L. E., Jarausch, D.-D., Higler, R., Hüttner, S., Leijtens, T., Stranks, S. D., Snaith, H. J., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5005285 · Cited by 1,753
Cited by
Brenner, T. M., Egger, D. A., Kronik, L., Hodes, G., & Cahen, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.7 · Cited by 1,557
Cubic Perovskite Structure of Black Formamidinium Lead Iodide, α-[HC(NH2)2]PbI3, at 298 K
Weller, M. T., Weber, O. J., Frost, J. M., & Walsh, A. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01432 · Cited by 580
Zhao, Y.-C., Zhou, W.-K., Zhou, X., Liu, K.-H., Yu, D.-P., & Zhao, Q. (2016) · Light: Science & Applications · doi:10.1038/lsa.2016.243 · Cited by 478
Leguy, A. M. A., Goñi, A. R., Frost, J. M., Skelton, J., Brivio, F., Rodríguez-Martínez, X., Weber, O. J., Pallipurath, A., Alonso, M. I., Campoy-Quiles, M., et al. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp03474h · Cited by 459
Nonradiative Losses in Metal Halide Perovskites
Stranks, S. D. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00239 · Cited by 336
Metadata
- Authors
- Gottesman, R., Gouda, L., Kalanoor, B. S., Haltzi, E., Tirosh, S., Rosh-Hodesh, E., Tischler, Y., Zaban, A., Quarti, C., Mosconi, E., & De Angelis, F.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-08
- Volume
- 6
- Issue
- 12
- Pages
- 2332-2338
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W1449148913
- Cited by
- 222
- References
- 3
- FWCI
- 15.88
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Gottesman, R., Gouda, L., Kalanoor, B. S., Haltzi, E., Tirosh, S., Rosh-Hodesh, E., Tischler, Y., Zaban, A., Quarti, C., Mosconi, E., & De Angelis, F. (2015). Photoinduced Reversible Structural Transformations in Free-Standing CH3NH3PbI3 Perovskite Films. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.5b00994
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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