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Enhanced Organo-Metal Halide Perovskite Photoluminescence from Nanosized Defect-Free Crystallites and Emitting Sites
Abstract
Photoluminescence (PL) of organo-metal halide perovskite semiconductors can be enhanced by several orders of magnitude by exposure to visible light. We applied PL microscopy and super-resolution optical imaging to investigate this phenomenon with spatial resolution better than 10 nm using films of CH3NH3PbI3 prepared by the equimolar solution-deposition method, resulting in crystals of different sizes. We found that PL of ∼100 nm crystals enhances much faster than that of larger, micrometer-sized ones. This crystal-size dependence of the photochemical light passivation of charge traps responsible for PL quenching allowed us to conclude that traps are present in the entire crystal volume rather than at the surface only. Because of this effect, "dark" micrometer-sized perovskite crystals can be converted into highly luminescent smaller ones just by mechanical grinding. Super-resolution optical imaging shows spatial inhomogeneity of the PL intensity within perovskite crystals and the existence of <100 nm-sized localized emitting sites. The possible origin of these sites is discussed.
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Citations
Cites
Impact of microstructure on local carrier lifetime in perovskite solar cells
de Quilettes, D. W., Vorpahl, S. M., Stranks, S. D., Nagaoka, H., Eperon, G. E., Ziffer, M. E., Snaith, H. J., & Ginger, D. S. (2015) · Science · doi:10.1126/science.aaa5333 · Cited by 2,198
Deschler, F., Price, M., Pathak, S., Klintberg, L. E., Jarausch, D.-D., Higler, R., Hüttner, S., Leijtens, T., Stranks, S. D., Snaith, H. J., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5005285 · Cited by 1,753
Cited by
Fang, H.-H., Adjokatse, S., Wei, H., Yang, J., Blake, G. R., Huang, J., Even, J., & Loi, M. A. (2016) · Science Advances · doi:10.1126/sciadv.1600534 · Cited by 369
Structural and Photophysical Properties of Methylammonium Lead Tribromide (MAPbBr3) Single Crystals
Wang, K.-H., Li, L.-C., Shellaiah, M., & Wen Sun, K. (2017) · Scientific Reports · doi:10.1038/s41598-017-13571-1 · Cited by 271
Metadata
- Authors
- Tian, Y., Merdasa, A., Unger, E., Abdellah, M., Zheng, K., McKibbin, S., Mikkelsen, A., Pullerits, T., Yartsev, A., Sundström, V., & Scheblykin, I. G.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-06
- Volume
- 6
- Issue
- 20
- Pages
- 4171-4177
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2175537103
- Cited by
- 180
- References
- 2
- FWCI
- 12.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Tian, Y., Merdasa, A., Unger, E., Abdellah, M., Zheng, K., McKibbin, S., Mikkelsen, A., Pullerits, T., Yartsev, A., Sundström, V., & Scheblykin, I. G. (2015). Enhanced Organo-Metal Halide Perovskite Photoluminescence from Nanosized Defect-Free Crystallites and Emitting Sites. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.5b02033
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