Cited by 12Advancements in Battery MaterialsSupercapacitor Materials and FabricationBattery Modeling and Management

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

Study on Tin–Cobalt Bimetallic Phosphide Nanoparticles as a Negative Electrode of Sodium-Ion Batteries

Abstract

Tin phosphide (Sn 4 P 3 ) holds great promise because sodium-ion batteries use this material as an anode with impressive theoretical capacity. In this paper, it is reported that Co-doped Sn 4 P 3 is embedded into carbon-based materials and SnCoP/C with a porous skeleton is prepared. As a result, SnCoP/C-2, as the material utilized in sodium-ion battery anodes, exhibits reversible capacities at 415.6, 345.9, and 315.6 mAh g -1 at current intensities of 0.5, 1.0, and 2.0 A g -1 , respectively. The electrochemical reversibility, cycle stability, and rate performance of SnCoP/C samples are obviously better than those of Sn 4 P 3 /C. Cobalt in SnCoP/C stabilizes the conductive matrix of tin phosphide and promotes the diffusion kinetics of sodium. These results show that, with an appropriate amount of cobalt doping, highly dispersed nanoparticles can be formed in the tin phosphide matrix, which can significantly enhance the cycle stability of tin-based electrode materials.

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Crossref · 10.1021/acs.langmuir.4c00794

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Metadata

Authors
Liu, S., Feng, K., Xu, W., & Tong, J.
Affiliations
Shaanxi University of Science and Technology (CN)
Corresponding author
Liu, Shuling
Venue
Langmuir
Published
2024-05-02
Volume
40
Issue
19
Pages
10270-10280
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W4396574036
Cited by
12
References
42
Citations by year
2026: 3 · 2025: 8 · 2024: 1
FWCI
1.24
Type
journal article
Language
en
Open access
closed
Locations
  • Langmuir (publishedVersion)
  • PubMed (publishedVersion)
Funders
National Natural Science Foundation of China (22278255)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
  • Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
Keywords
tin phosphide, Sn4P3, cobalt doping, sodium-ion battery anodes, porous skeleton, cycling stability, rate capability, electrochemical reversibility

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