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Mapping Nanoscale Hotspots with Single-Molecule Emitters Assembled into Plasmonic Nanocavities Using DNA Origami
Open accessAbstract
Abstract Fabricating nanocavities in which optically active single quantum emitters are precisely positioned is crucial for building nanophotonic devices. Here we show that self-assembly based on robust DNA-origami constructs can precisely position single molecules laterally within sub-5 nm gaps between plasmonic substrates that support intense optical confinement. By placing single-molecules at the center of a nanocavity, we show modification of the plasmon cavity resonance before and after bleaching the chromophore and obtain enhancements of ≥4 × 103 with high quantum yield (≥50%). By varying the lateral position of the molecule in the gap, we directly map the spatial profile of the local density of optical states with a resolution of ±1.5 nm. Our approach introduces a straightforward noninvasive way to measure and quantify confined optical modes on the nanoscale.
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Controlling the dynamics of spontaneous emission from quantum dots by photonic crystals
Lodahl, P., Floris van Driel, A., Nikolaev, I. S., Irman, A., Overgaag, K., Vanmaekelbergh, D., & Vos, W. L. (2004) · Nature · doi:10.1038/nature02772 · Cited by 1,286
Metadata
- Authors
- Chikkaraddy, R., Turek, V. A., Kongsuwan, N., Benz, F., Carnegie, C., van de Goor, T., de Nijs, B., Demetriadou, A., Hess, O., Keyser, U. F., & Baumberg, J. J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-12-05
- Volume
- 18
- Issue
- 1
- Pages
- 405-411
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2767185672
- Cited by
- 174
- References
- 1
- FWCI
- 6.87
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- CoChat. (2026). Citation check: Mapping Nanoscale Hotspots with Single-Molecule Emitters Assembled into Plasmonic Nanocavities Using DNA Origami. https://app.cochat.ai/papers/10.1021/acs.nanolett.7b04283
- The paper
- Chikkaraddy, R., Turek, V. A., Kongsuwan, N., Benz, F., Carnegie, C., van de Goor, T., de Nijs, B., Demetriadou, A., Hess, O., Keyser, U. F., & Baumberg, J. J. (2018). Mapping Nanoscale Hotspots with Single-Molecule Emitters Assembled into Plasmonic Nanocavities Using DNA Origami. Nano Letters. https://doi.org/10.1021/acs.nanolett.7b04283
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.