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Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair

Open access
Bohn, Bernhard J., Tong, Yu, Gramlich, Moritz, Lai, May Ling, Döblinger, Markus, Wang, Kun, Hoye, Robert L. Z., Müller-Buschbaum, Peter, Stranks, Samuel D., Urban, Alexander S., Polavarapu, Lakshminarayana, Feldmann, Jochen·2018·Nano Letters

Abstract

Abstract The easily tunable emission of halide perovskite nanocrystals throughout the visible spectrum makes them an extremely promising material for light-emitting applications. Whereas high quantum yields and long-term colloidal stability have already been achieved for nanocrystals emitting in the red and green spectral range, the blue region currently lags behind with low quantum yields, broad emission profiles, and insufficient colloidal stability. In this work, we present a facile synthetic approach for obtaining two-dimensional CsPbBr3 nanoplatelets with monolayer-precise control over their thickness, resulting in sharp photoluminescence and electroluminescence peaks with a tunable emission wavelength between 432 and 497 nm due to quantum confinement. Subsequent addition of a PbBr2-ligand solution repairs surface defects likely stemming from bromide and lead vacancies in a subensemble of weakly emissive nanoplatelets. The overall photoluminescence quantum yield of the blue-emissive colloidal dispersions is consequently enhanced up to a value of 73 ± 2%. Transient optical spectroscopy measurements focusing on the excitonic resonances further confirm the proposed repair process. Additionally, the high stability of these nanoplatelets in films and to prolonged ultraviolet light exposure is shown.

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Metadata

Authors
Bohn, B. J., Tong, Y., Gramlich, M., Lai, M. L., Döblinger, M., Wang, K., Hoye, R. L. Z., Müller-Buschbaum, P., Stranks, S. D., Urban, A. S., Polavarapu, L., & Feldmann, J.
Venue
Nano Letters
Published
2018-07-10
Volume
18
Issue
8
Pages
5231-5238
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2819236562
Cited by
541
References
2
FWCI
21.45
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair. https://app.cochat.ai/papers/10.1021/acs.nanolett.8b02190
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Bohn, B. J., Tong, Y., Gramlich, M., Lai, M. L., Döblinger, M., Wang, K., Hoye, R. L. Z., Müller-Buschbaum, P., Stranks, S. D., Urban, A. S., Polavarapu, L., & Feldmann, J. (2018). Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair. Nano Letters. https://doi.org/10.1021/acs.nanolett.8b02190

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