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Near-Direct Bandgap WSe2/ReS2 Type-II pn Heterojunction for Enhanced Ultrafast Photodetection and High-Performance Photovoltaics

Open access
Varghese, Abin, Saha, Dipankar, Thakar, Kartikey, Jindal, Vishwas, Ghosh, Sayantan, Medhekar, Nikhil V, Ghosh, Sandip, Lodha, Saurabh·2020·Nano Letters

Abstract

Pn heterojunctions comprising layered van der Waals (vdW) semiconductors have been used to demonstrate current-rectifiers, photodetectors, and photovoltaic devices. However, a direct or near-direct heterointerface bandgap for enhanced photogeneration in high light-absorbing few-layer vdW materials remains unexplored. In this work, for the first time, density functional theory calculations show that the heterointerface of few-layer group-6 transition metal dichalcogenide (TMD) WSe 2 with group-7 ReS 2 results in a sizable (0.7 eV) near-direct type-II bandgap. The interlayer IR bandgap is confirmed through IR photodetection, and microphotoluminescence measurements demonstrate type-II alignment. Few-layer flakes exhibit ultrafast response time (5 μs), high responsivity (3 A/W), and large photocurrent-generation and responsivity-enhancement at the hetero-overlap region (10–100×). Large open-circuit voltage of 0.64 V and short-circuit current of 2.6 μA enable high output electrical power. Finally, long-term air-stability and facile single contact metal fabrication process make the multifunctional few-layer WSe 2 /ReS 2 heterostructure diode technologically promising for next-generation optoelectronics.

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Metadata

Authors
Varghese, A., Saha, D., Thakar, K., Jindal, V., Ghosh, S., Medhekar, N. V., Ghosh, S., & Lodha, S.
Venue
Nano Letters
Published
2020-02-20
Volume
20
Issue
3
Pages
1707-1717
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W3007474645
Cited by
266
References
58
FWCI
14.17
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Near-Direct Bandgap WSe2/ReS2 Type-II pn Heterojunction for Enhanced Ultrafast Photodetection and High-Performance Photovoltaics. https://app.cochat.ai/papers/10.1021/acs.nanolett.9b04879
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Varghese, A., Saha, D., Thakar, K., Jindal, V., Ghosh, S., Medhekar, N. V., Ghosh, S., & Lodha, S. (2020). Near-Direct Bandgap WSe2/ReS2 Type-II pn Heterojunction for Enhanced Ultrafast Photodetection and High-Performance Photovoltaics. Nano Letters. https://doi.org/10.1021/acs.nanolett.9b04879

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