Advanced Catalysts for Photoelectrochemical Water Splitting
Abstract
Photoelectrochemical (PEC) water splitting offers a sparkling and sustainable strategy for hydrogen generation, and significant research for enhancing the conversion efficiency of electrocatalysts is underway, since a huge number of publications have been reported in this field. Hence, it is urgent to write a comprehensive and updated review in order to highlight the latest progress in the design, fabrication, and modification of electrocatalysts for high-efficiency PEC water splitting. In this review, we describe the basic mechanism of PEC water splitting utilizing electrocatalysts in detail. Further, we highlighted the recent advancements in the design, fabrication, and modification of high-efficiency electrocatalysts for energy conversion. In addition, the catalysts’ surface passivation, heterojunction constructions, defect engineering, and photovoltage and photocurrent enhancements are also highlighted.
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The low electronic conductivity, wide band gap, rapid charge carrier recombination, and small accessible surface active sites of carbon nitride greatly limit its application in water splitting and photosynthesis.
“Unfortunately, the low electronic conductivity, wide band gap, rapid charge carrier recombination behavior, as well as the fairly small accessible surface active sites, have greatly limited its application in water splitting and photosynthesis [6, 7].”
From Unveiling N-doped carbon nitride aerogel for efficient electrocatalytic water splitting application (2025) · cites this paper as [6]
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Unveiling N-doped carbon nitride aerogel for efficient electrocatalytic water splitting application
Jadhav, S. B., Thakur, M., & Sarawade, P. B. (2025) · Journal of Porous Materials · doi:10.1007/s10934-024-01711-8 · Cited by 4 · see citing works
- Authors
- Marwat, M. A., Humayun, M., Afridi, M. W., Zhang, H., Abdul Karim, M. R., Ashtar, M., Usman, M., Waqar, S., Ullah, H., Wang, C., & Luo, W.
- Affiliations
- Ghulam Ishaq Khan Institute of Engineering Sciences and Technology (PK)
- Wuhan National Laboratory for Optoelectronics (CN)
- State Key Laboratory of Materials Processing and Die & Mould Technology (CN)
- Department of Materials Science and Engineering, Ghulam Ishaq Khan Institute of Engineering Sciences and Technology, Topi 23640, Khyber Pakhtunkhwa, Pakistan
- Huazhong University of Science and Technology (CN)
- King Fahd University of Petroleum and Minerals (SA)
- Shandong University (CN)
- Wuhan University of Technology (CN)
- Corresponding author
- Wang, Chundong
- Luo, Wei
- ORCID
- Venue
- ACS Applied Energy Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-10-26
- Volume
- 4
- Issue
- 11
- Pages
- 12007-12031
- ISSN
- 2574-0962 (ISSN-L)
- OpenAlex
- W3209712157
- Cited by
- 191
- References
- 0
- Citations by year
- 2026: 17 · 2025: 44 · 2024: 45 · 2023: 56 · 2022: 29
- FWCI
- 6.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Applied Energy Materials (publishedVersion)
- Funders
- Ministry of Science and Technology of the People's Republic of China (2017YFE0120500, 2018YFA0702100)
- Saudi Aramco (ORCP2390)
- National Natural Science Foundation of China (11874169, 51972129)
- South Xinjiang Innovation and Development Program of Key Industries of Xinjiang Production and Construction Corps (2020DB002)
- Hubei Province (2020BAB079)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Iron oxide chemistry and applications
- Keywords
- photoelectrochemical water splitting, electrocatalysts, hydrogen production, surface passivation, heterojunction, defect engineering, photovoltage enhancement, photocurrent enhancement, energy conversion
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