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Creating a Stable Oxide at the Surface of Black Phosphorus
Abstract
The stability of the surface of in situ cleaved black phosphorus crystals upon exposure to atmosphere is investigated with synchrotron-based photoelectron spectroscopy. After 2 days atmosphere exposure a stable subnanometer layer of primarily P2O5 forms at the surface. The work function increases by 0.1 eV from 3.9 eV for as-cleaved black phosphorus to 4.0 eV after formation of the 0.4 nm thick oxide, with phosphorus core levels shifting by <0.1 eV. The results indicate minimal charge transfer, suggesting that the oxide layer is suitable for passivation or as an interface layer for further dielectric deposition.
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Cited by
Phosphorene: from theory to applications
Carvalho, A., Wang, M., Zhu, X., Rodin, A. S., Su, H., & Castro Neto, A. H. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.61 · Cited by 1,159
Self-citationLight‐Induced Ambient Degradation of Few‐Layer Black Phosphorus: Mechanism and Protection
Zhou, Q., Chen, Q., Tong, Y., & Wang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605168 · Cited by 658
Black Phosphorus Rediscovered: From Bulk Material to Monolayers
Gusmão, R., Sofer, Z., & Pumera, M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610512 · Cited by 521
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
Ryder, C. R., Wood, J. D., Wells, S. A., & Hersam, M. C. (2016) · ACS Nano · doi:10.1021/acsnano.6b01091 · Cited by 283
Metadata
- Authors
- Edmonds, M. T., Tadich, A., Carvalho, A., Ziletti, A., O’Donnell, K. M., Koenig, S. P., Coker, D. F., Özyilmaz, B., Neto, A. H. C., & Fuhrer, M. S.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-30
- Volume
- 7
- Issue
- 27
- Pages
- 14557-14562
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W832270762
- Cited by
- 365
- References
- 0
- FWCI
- 17.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Edmonds, M. T., Tadich, A., Carvalho, A., Ziletti, A., O’Donnell, K. M., Koenig, S. P., Coker, D. F., Özyilmaz, B., Neto, A. H. C., & Fuhrer, M. S. (2015). Creating a Stable Oxide at the Surface of Black Phosphorus. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.5b01297
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