The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Indirect Z-Scheme BiOI/g-C3N4 Photocatalysts with Enhanced Photoreduction CO2 Activity under Visible Light Irradiation
Abstract
Rational design and construction of Z-scheme photocatalysts has received much attention in the field of CO2 reduction because of its great potential to solve the current energy and environmental crises. In this study, a series of Z-scheme BiOI/g-C3N4 photocatalysts are synthesized and their photocatalytic performance for CO2 reduction to produce CO, H2 and/or CH4 is evaluated under visible light irradiation (λ > 400 nm). The results show that the as-synthesized composites exhibit more highly efficient photocatalytic activity than pure g-C3N4 and BiOI and that the product yields change remarkably depending on the reaction conditions such as irradiation light wavelength. Emphasis is placed on identifying how the charge transfers across the heterojunctions and an indirect Z-scheme charge transfer mechanism is verified by detecting the intermediate I3(-) ions. The reaction mechanism is further proposed based on the detection of the intermediate (•)OH and H2O2. This work may be useful for rationally designing of new types of Z-scheme photocatalyst and provide some illuminating insights into the Z-scheme transfer mechanism.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
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Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Direct Z-scheme photocatalysts: Principles, synthesis, and applications
Xu, Q., Zhang, L., Yu, J., Wageh, S., Al-Ghamdi, A. A., & Jaroniec, M. (2018) · Materials Today · doi:10.1016/j.mattod.2018.04.008 · Cited by 1,635
Self-citationLiao, G., Gong, Y., Zhang, L., Gao, H., Yang, G.-J., & Fang, B. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00717b · Cited by 1,075
Self-citationZ‐Scheme Photocatalytic Systems for Carbon Dioxide Reduction: Where Are We Now?
Zhang, W., Mohamed, A. R., & Ong, W. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201914925 · Cited by 667
Metadata
- Authors
- Wang, J.-C., Yao, H.-C., Fan, Z.-Y., Zhang, L., Wang, J.-S., Zang, S.-Q., & Li, Z.-J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-03
- Volume
- 8
- Issue
- 6
- Pages
- 3765-3775
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2267752385
- Cited by
- 618
- References
- 2
- FWCI
- 22.44
- Type
- journal article
- Language
- en
- Open access
- closed
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