The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Hollow Structured Micro/Nano MoS2 Spheres for High Electrocatalytic Activity Hydrogen Evolution Reaction
Abstract
Molybdenum disulfide (MoS2) has attracted extensive attention as a non-noble metal electrocatalyst for hydrogen evolution reaction (HER). Controlling the skeleton structure at the nanoscale is paramount to increase the number of active sites at the surface. However, hydrothermal synthesis favors the presence of the basal plane, limiting the efficiency of catalytic reaction. In this work, perfect hollow MoS2 microspheres capped by hollow MoS2 nanospheres (hH-MoS2) were obtained for the first time, which creates an opportunity for improving the HER electrocatalytic performance. Benefiting from the controllable hollow skeleton structure and large exposed edge sites, high-efficiency HER activity was obtained for stacked MoS2 thin shells with a mild degree of disorder, proving the presence of rich active sites and the validity of the combined structure. In general, the obtained hollow micro/nano MoS2 nanomaterial exhibits optimized electrocatalytic activity for HER with onset overpotential as low as 112 mV, low Tafel slope of 74 mV decade(-1), high current density of 10 mA cm(-2) at η = 214 mV, and high TOF of 0.11 H2 s(-1) per active site at η = 200 mV.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Alternative energy technologies
Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Xie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
Sheng, W., Gasteiger, H. A., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483106 · Cited by 1,829
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Kibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408222 · Cited by 1,048
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
Chang, Y., Lin, C., Chen, T., Hsu, C., Lee, Y., Zhang, W., Wei, K., & Li, L. (2013) · Advanced Materials · doi:10.1002/adma.201202920 · Cited by 744
Youn, D. H., Han, S., Kim, J. Y., Kim, J. Y., Park, H., Choi, S. H., & Lee, J. S. (2014) · ACS Nano · doi:10.1021/nn5012144 · Cited by 559
Chung, D. Y., Park, S.-K., Chung, Y.-H., Yu, S.-H., Lim, D.-H., Jung, N., Ham, H. C., Park, H.-Y., Piao, Y., Yoo, S. J., et al. (2014) · Nanoscale · doi:10.1039/c3nr05228a · Cited by 287
Zhu, H., Du, M., Zhang, M., Zou, M., Yang, T., Wang, S., Yao, J., & Guo, B. (2014) · Chem. Commun. · doi:10.1039/c4cc06480a · Cited by 125
Self-citation
Cited by
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Roadmap and Direction toward High-Performance MoS 2 Hydrogen Evolution Catalysts
Cao, Y. (2021) · ACS Nano · doi:10.1021/acsnano.1c01879 · Cited by 405
Structural and Electronic Optimization of MoS 2 Edges for Hydrogen Evolution
Wang, H., Xiao, X., Liu, S., Chiang, C.-L., Kuai, X., Peng, C.-K., Lin, Y.-C., Meng, X., Zhao, J., Choi, J., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b09932 · Cited by 383
Nanoengineering Carbon Spheres as Nanoreactors for Sustainable Energy Applications
Tian, H., Liang, J., & Liu, J. (2019) · Advanced Materials · doi:10.1002/adma.201903886 · Cited by 348
Kuang, P., Tong, T., Fan, K., & Yu, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02225 · Cited by 334
Metadata
- Authors
- Guo, B., Yu, K., Li, H., Song, H., Zhang, Y., Lei, X., Fu, H., Tan, Y., & Zhu, Z.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-16
- Volume
- 8
- Issue
- 8
- Pages
- 5517-5525
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2277107450
- Cited by
- 203
- References
- 18
- FWCI
- 10.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
