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Cobalt-Based Layered Metal–Organic Framework as an Ultrahigh Capacity Supercapacitor Electrode Material
Abstract
Metal-organic frameworks (MOFs) have recently received increasing interest due to their potential application in the energy storage and conversion field. Herein, cobalt-based layered MOF ({[Co(Hmt)(tfbdc)(H2O)2]·(H2O)2}n, Co-LMOF; Hmt = hexamethylenetetramine; H2tfbdc = 2,3,5,6-tetrafluoroterephthalic acid) has been evaluated as an electrode material for supercapacitors. The Co-LMOF electrode exhibits a high specific capacitance and excellent cycling stability. Its maximum specific capacitance is 2474 F g(-1) at a current density of 1 A g(-1), and the specific capacitance retention is about 94.3% after 2000 cycles. The excellent electrochemical property may be ascribed to the intrinsic nature of Co-LMOF, enough space available for the storage and diffusion of the electrolyte, and the particles of nanoscale size.
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Cited by
Recent progress in metal-organic frameworks as active materials for supercapacitors
Wang, K.-B., Xun, Q., & Zhang, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2019.100025 · Cited by 474
Aboelazm, E. A. A., Ali, G. A. M., Algarni, H., Yin, H., Zhong, Y. L., & Chong, K. F. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b03306 · Cited by 116
Metadata
- Authors
- Liu, X., Shi, C., Zhai, C., Cheng, M., Liu, Q., & Wang, G.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-10
- Volume
- 8
- Issue
- 7
- Pages
- 4585-4591
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2256578749
- Cited by
- 418
- References
- 0
- FWCI
- 14.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, X., Shi, C., Zhai, C., Cheng, M., Liu, Q., & Wang, G. (2016). Cobalt-Based Layered Metal–Organic Framework as an Ultrahigh Capacity Supercapacitor Electrode Material. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.5b10781
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