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Multicolored, Low-Power, Flexible Electrochromic Devices Based on Ion Gels

Moon, Hong Chul, Kim, Chang-Hyun, Lodge, Timothy P., Frisbie, C. Daniel·2016·ACS Applied Materials & Interfaces

Abstract

Ion gels composed of a copolymer and a room temperature ionic liquid are versatile solid-state electrolytes with excellent features including high ionic conductivity, nonvolatility, easily tunable mechanical properties, good flexibility and solution processability. Ion gels can be functionalized by incorporating redox-active species such as electrochemiluminescent (ECL) luminophores or electrochromic (EC) dyes. Here, we enhance the functionality of EC gels for realizing multicolored EC devices (ECDs), either by controlling the chemical equilibrium between a monomer and dimer of a colored EC species, or by modifying the molecular structures of the EC species. All devices in this work are conveniently fabricated by a "cut-and-stick" strategy, and require very low power for maintaining the colored state [i.e., 90 μW/cm(2) (113 μA/cm(2) at -0.8 V) for blue, 4 μW/cm(2) (10 μA/cm(2) at -0.4 V) for green, and 32 μW/cm(2) (79 μA/cm(2) at -0.4 V) for red ECD]. We also successfully demonstrate a patterned, multicolored, flexible ECD on plastic. Overall, these results suggest that gel-based ECDs have significant potential as low power displays in printed electronics powered by thin-film batteries.

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Metadata

Authors
Moon, H. C., Kim, C.-H., Lodge, T. P., & Frisbie, C. D.
Venue
ACS Applied Materials & Interfaces
Published
2016-03-01
Volume
8
Issue
9
Pages
6252-6260
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2292719129
Cited by
263
References
26
FWCI
20.09
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Multicolored, Low-Power, Flexible Electrochromic Devices Based on Ion Gels. https://app.cochat.ai/papers/10.1021/acsami.6b01307
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Moon, H. C., Kim, C.-H., Lodge, T. P., & Frisbie, C. D. (2016). Multicolored, Low-Power, Flexible Electrochromic Devices Based on Ion Gels. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b01307

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