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A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film
Abstract
Organic–inorganic hybrid lead organohalide perovskites are inexpensive materials for high-efficiency photovoltaic solar cells, optical properties, and superior electrical conductivity. However, the fabrication of their quantum dots (QDs) with uniform ultrasmall particles is still a challenge. Here we use oriented microporous metal–organic framework (MOF) thin film prepared by liquid phase epitaxy approach as a template for CH 3 NH 3 PbI 2 X (X = Cl, Br, and I) perovskite QDs fabrication. By introducing the PbI 2 and CH 3 NH 3 X (MAX) precursors into MOF HKUST-1 (Cu 3 (BTC) 2, BTC = 1,3,5-benzene tricarboxylate) thin film in a stepwise approach, the resulting perovskite MAPbI 2 X (X = Cl, Br, and I) QDs with uniform diameters of 1.5–2 nm match the pore size of HKUST-1. Furthermore, the photoluminescent properties and stability in the moist air of the perovskite QDs loaded HKUST-1 thin film were studied. This confined fabrication strategy demonstrates that the perovskite QDs loaded MOF thin film will be insensitive to air exposure and offers a novel means of confining the uniform size of the similar perovskite QDs according to the oriented porous MOF materials.
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Cites
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
Zhu, H., Fu, Y., Meng, F., Wu, X., Gong, Z., Ding, Q., Gustafsson, M. V., Trinh, M. T., Jin, S., & Zhu, X.-Y. (2015) · Nature Materials · doi:10.1038/nmat4271 · Cited by 2,836
Zhang, H., Ma, Z., Duan, J., Liu, H., Liu, G., Wang, T., Chang, K., Li, M., Shi, L., Meng, X., et al. (2016) · ACS Nano · doi:10.1021/acsnano.5b05728 · Cited by 491
Cited by
Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Atomic-scale microstructure of metal halide perovskite
Rothmann, M. U., Kim, J. S., Borchert, J., Lohmann, K. B., O’Leary, C. M., Sheader, A. A., Clark, L., Snaith, H. J., Johnston, M. B., Nellist, P. D., et al. (2020) · Science · doi:10.1126/science.abb5940 · Cited by 319
Sun, J., Rabouw, F. T., Yang, X., Huang, X., Jing, X., Ye, S., & Zhang, Q. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201704371 · Cited by 267
Metadata
- Authors
- Chen, Z., Gu, Z.-G., Fu, W.-Q., Wang, F., & Zhang, J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-10-14
- Volume
- 8
- Issue
- 42
- Pages
- 28737-28742
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2531709650
- Cited by
- 171
- References
- 2
- FWCI
- 6.56
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, Z., Gu, Z.-G., Fu, W.-Q., Wang, F., & Zhang, J. (2016). A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b11712
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