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A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film

Chen, Zheng, Gu, Zhi-Gang, Fu, Wen-Qiang, Wang, Fei, Zhang, Jian·2016·ACS Applied Materials & Interfaces

Abstract

Organic–inorganic hybrid lead organohalide perovskites are inexpensive materials for high-efficiency photovoltaic solar cells, optical properties, and superior electrical conductivity. However, the fabrication of their quantum dots (QDs) with uniform ultrasmall particles is still a challenge. Here we use oriented microporous metal–organic framework (MOF) thin film prepared by liquid phase epitaxy approach as a template for CH 3 NH 3 PbI 2 X (X = Cl, Br, and I) perovskite QDs fabrication. By introducing the PbI 2 and CH 3 NH 3 X (MAX) precursors into MOF HKUST-1 (Cu 3 (BTC) 2, BTC = 1,3,5-benzene tricarboxylate) thin film in a stepwise approach, the resulting perovskite MAPbI 2 X (X = Cl, Br, and I) QDs with uniform diameters of 1.5–2 nm match the pore size of HKUST-1. Furthermore, the photoluminescent properties and stability in the moist air of the perovskite QDs loaded HKUST-1 thin film were studied. This confined fabrication strategy demonstrates that the perovskite QDs loaded MOF thin film will be insensitive to air exposure and offers a novel means of confining the uniform size of the similar perovskite QDs according to the oriented porous MOF materials.

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Metadata

Authors
Chen, Z., Gu, Z.-G., Fu, W.-Q., Wang, F., & Zhang, J.
Venue
ACS Applied Materials & Interfaces
Published
2016-10-14
Volume
8
Issue
42
Pages
28737-28742
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2531709650
Cited by
171
References
2
FWCI
6.56
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film. https://app.cochat.ai/papers/10.1021/acsami.6b11712
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Chen, Z., Gu, Z.-G., Fu, W.-Q., Wang, F., & Zhang, J. (2016). A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b11712

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