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Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction

Chi, Jun, Yu, Hongmei, Qin, Bowen, Fu, Li, Jia, Jia, Yi, Baolian, Shao, Zhigang·2017·ACS Applied Materials & Interfaces

Abstract

Employing a low-cost and highly efficient electrocatalyst to replace Ir-based catalysts for oxygen evolution reaction (OER) has drawn increasing interest in renewable energy storage. In this work, a vertically aligned FeOOH/NiFe layered double hydroxides (LDHs) nanosheets supported on Ni foam (VA FeOOH/NiFe LDHs-NF) is prepared as a highly effective OER electrode in alkaline electrolyte. The VA FeOOH/NiFe LDHs-NF represents nanosheet arrays on nickel foam with some interspace among them. The vertically aligned and interlayer-structured architecture is binder-free and contributes to facile strain relaxation, relieving the exfoliation of the catalysts layer caused by the oxygen evolution process. The as-prepared electrode shows current densities of 10 and 500 mA cm –2 at overpotentials of 208 and 288 mV, and good stability in a half-cell electrolyzer. Besides, the alkaline polymer electrolyte water electrolyzer (APEWE) with this electrode showed 1.71 V at 200 mA cm –2, and 2.041 V at 500 mA cm –2, exhibiting the corresponding energy efficiency of 86.0% and 72.0% (based on the lower heating value of hydrogen), which is better than the typical commercial alkaline water electrolyzer.

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Metadata

Authors
Chi, J., Yu, H., Qin, B., Fu, L., Jia, J., Yi, B., & Shao, Z.
Venue
ACS Applied Materials & Interfaces
Published
2016-12-22
Volume
9
Issue
1
Pages
464-471
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2567607482
Cited by
214
References
4
FWCI
6.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction. https://app.cochat.ai/papers/10.1021/acsami.6b13360
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Chi, J., Yu, H., Qin, B., Fu, L., Jia, J., Yi, B., & Shao, Z. (2017). Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b13360

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