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Cited by 187

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Graphene-Scaffolded Na3V2(PO4)3 Microsphere Cathode with High Rate Capability and Cycling Stability for Sodium Ion Batteries

Zhang, Jiexin, Fang, Yongjin, Xiao, Lifen, Qian, Jiangfeng, Cao, Yuliang, Ai, Xinping, Yang, Hanxi·2017·ACS Applied Materials & Interfaces

Abstract

High voltage, high rate, and cycling-stable cathodes are urgently needed for development of commercially viable sodium ion batteries (SIBs). Herein, we report a facile spray-drying method to synthesize graphene-scaffolded Na 3 V 2 (PO 4 ) 3 microspheres (NVP@rGO), in which nanocrystalline Na 3 V 2 (PO 4 ) 3 is embedded in graphene sheets to form porous microspheres. Benefiting from the highly conductive graphene framework and porous structure, the NVP@rGO material exhibits a high reversible capacity (115 mAh g –1 at 0.2 C), long-term cycle life (81% of capacity retention up to 3000 cycles at 5 C), and excellent rate performance (44 mAh g –1 at 50 C). The electrochemical properties of a full Na-ion cell with the NVP@rGO cathode and Sb/C anode are also investigated. The present results suggest promising applications of the NVP@rGO material as a high performance cathode for sodium ion batteries.

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Metadata

Authors
Zhang, J., Fang, Y., Xiao, L., Qian, J., Cao, Y., Ai, X., & Yang, H.
Venue
ACS Applied Materials & Interfaces
Published
2017-02-17
Volume
9
Issue
8
Pages
7177-7184
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2587601345
Cited by
187
References
1
FWCI
11.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Graphene-Scaffolded Na3V2(PO4)3 Microsphere Cathode with High Rate Capability and Cycling Stability for Sodium Ion Batteries. https://app.cochat.ai/papers/10.1021/acsami.6b16000
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Zhang, J., Fang, Y., Xiao, L., Qian, J., Cao, Y., Ai, X., & Yang, H. (2017). Graphene-Scaffolded Na3V2(PO4)3 Microsphere Cathode with High Rate Capability and Cycling Stability for Sodium Ion Batteries. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b16000

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