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Synthesis and Stabilization of Colloidal Perovskite Nanocrystals by Multidentate Polymer Micelles
Abstract
Lead halide perovskites have emerged as low-cost, high-performance optical and optoelectronic materials, however, their material stability has been a limiting factor for broad applications. Here, we demonstrate stable core-shell colloidal perovskite nanocrystals using a novel, facile and low-cost copolymer templated synthesis approach. The block copolymer serves as a confined nanoreactor during perovskite crystallization and passivates the perovskite surface by forming a multidentate capping shell, thus significantly improving its photostability in polar solvents. Meanwhile, the polymer nanoshell provides an additional layer for further surface modifications, paving the way to functional nanodevices that can be self-assembled or lithographically defined.
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Deschler, F., Price, M., Pathak, S., Klintberg, L. E., Jarausch, D.-D., Higler, R., Hüttner, S., Leijtens, T., Stranks, S. D., Snaith, H. J., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5005285 · Cited by 1,753
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Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Yoon, H. C., Lee, S., Song, J. K., Yang, H., & Do, Y. R. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b01014 · Cited by 143
Chen, T.-W., Ramachandran, R., Chen, S.-M., Kavitha, N., Dinakaran, K., Kannan, R., Anushya, G., Bhuvana, N., Jeyapragasam, T., Mariyappan, V., et al. (2020) · Catalysts · doi:10.3390/catal10080938 · Cited by 49
Metadata
- Authors
- Hou, S., Guo, Y., Tang, Y., & Quan, Q.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-05-25
- Volume
- 9
- Issue
- 22
- Pages
- 18417-18422
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2614760465
- Cited by
- 179
- References
- 1
- FWCI
- 9.29
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hou, S., Guo, Y., Tang, Y., & Quan, Q. (2017). Synthesis and Stabilization of Colloidal Perovskite Nanocrystals by Multidentate Polymer Micelles. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.7b03445
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