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High-Performance Cable-Type Flexible Rechargeable Zn Battery Based on MnO2@CNT Fiber Microelectrode

Wang, Kai, Zhang, Xiaohua, Han, Jianwei, Zhang, Xiong, Sun, Xianzhong, Li, Chen, Liu, Wenhao, Li, Qingwen, Ma, Yanwei·2018·ACS Applied Materials & Interfaces

Abstract

Nowadays, linear-shaped batteries have received increasing attentions because the unique one-dimensional architecture offers an omni-directional flexibility. We developed a cable-type flexible rechargeable Zn microbattery based on a microscale MnO 2 @carbon nanotube fiberlike composite cathode and Zn wire anode. The Zn–MnO 2 cable microbattery exhibits a large specific capacity, good rate performance, and cyclic stability. The capacity of Zn–MnO 2 cable batteries are 322 and 290 mAh/g based on MnO 2 with aqueous and gel polymer electrolyte, corresponding to the specific energy of 437 and 360 Wh/kg, respectively. Besides, the Zn–MnO 2 cable battery shows excellent flexibility, which can be folded into arbitrary shapes without sacrificing electrochemical performance. Furthermore, we studied electrochemical properties of Zn–MnO 2 cable microbatteries with different Zn salt electrolytes, such as Zn salt with small anions (ZnSO 4 or ZnCl 2, etc.) and Zn salt with bulky anions (Zn(CF 3 SO 3 ) 2, etc.). With the merits of impressive electrochemical performance and flexibility, this first flexible rechargeable Zn–MnO 2 cable-like battery presents a new approach to develop high-performance power sources for portable and wearable electronics.

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Metadata

Authors
Wang, K., Zhang, X., Han, J., Zhang, X., Sun, X., Li, C., Liu, W., Li, Q., & Ma, Y.
Venue
ACS Applied Materials & Interfaces
Published
2018-06-29
Volume
10
Issue
29
Pages
24573-24582
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2810395013
Cited by
232
References
1
FWCI
9.60
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: High-Performance Cable-Type Flexible Rechargeable Zn Battery Based on MnO2@CNT Fiber Microelectrode. https://app.cochat.ai/papers/10.1021/acsami.8b07756
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Wang, K., Zhang, X., Han, J., Zhang, X., Sun, X., Li, C., Liu, W., Li, Q., & Ma, Y. (2018). High-Performance Cable-Type Flexible Rechargeable Zn Battery Based on MnO2@CNT Fiber Microelectrode. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.8b07756

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