The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Highly Cuboid-Shaped Heterobimetallic Metal–Organic Frameworks Derived from Porous Co/ZnO/C Microrods with Improved Electromagnetic Wave Absorption Capabilities
Abstract
Metal-organic framework (MOF)-derived porous metal/C composites have drawn considerable attention from the microwave absorption field owing to their large pore volumes and surface areas. Exploring single-MOF-derived materials with high intensity and broadband absorption is largely needed but remains a challenge. Here, porous Co/ZnO/C (CZC) microrods were fabricated easily from cuboid-shaped heterobimetallic MOFs. CZC provides an efficient platform for integrating different semiconductors (ZnO), magnetic metal (Co), and carbon sources into one particle, which enhances the electromagnetic (EM) wave-absorbing ability. The carbonization temperature which is critical for EM parameters was studied in detail. CZC annealed at 700 °C outperformed those obtained at 600 or 800 °C in terms of microwave wave-absorbing properties. The reflection loss (RL) was optimized to -52.6 (or -20.6) dB at 12.1 (or 14.8) GHz with an effective bandwidth (RL ≤ -10 dB) of 4.9 (or 5.8) GHz at the coating thickness of 3.0 (or 2.5) mm. Such enhancement of EM wave-absorbing capabilities is ascribed to the well-built porous structure, dielectric loss, and magnetic loss. This work offers a new way to prepare porous magnetic metal/C composites with excellent microwave-absorbing properties starting from heterobimetallic MOFs.
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Characterization and properties of Zn/Co zeolitic imidazolate frameworks vs. ZIF-8 and ZIF-67
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Electromagnetic absorption materials: Current progress and new frontiers
Lv, H., Yang, Z., Pan, H., & Wu, R. (2022) · Progress in Materials Science · doi:10.1016/j.pmatsci.2022.100946 · Cited by 837
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Carbon-Based MOF Derivatives: Emerging Efficient Electromagnetic Wave Absorption Agents
Zhang, X., Qiao, J., Jiang, Y., Wang, F., Tian, X., Wang, Z., Wu, L., Liu, W., & Liu, J. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00658-8 · Cited by 409
Design and fabrication of superwetting fiber-based membranes for oil/water separation applications
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Metadata
- Authors
- Liao, Q., He, M., Zhou, Y., Nie, S., Wang, Y., Hu, S., Yang, H., Li, H., & Tong, Y.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-08-02
- Volume
- 10
- Issue
- 34
- Pages
- 29136-29144
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2885673267
- Cited by
- 355
- References
- 39
- FWCI
- 11.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liao, Q., He, M., Zhou, Y., Nie, S., Wang, Y., Hu, S., Yang, H., Li, H., & Tong, Y. (2018). Highly Cuboid-Shaped Heterobimetallic Metal–Organic Frameworks Derived from Porous Co/ZnO/C Microrods with Improved Electromagnetic Wave Absorption Capabilities. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.8b09093
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