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Self-Assembled Sandwich-like MXene-Derived Nanocomposites for Enhanced Electromagnetic Wave Absorption

Zhao, Guoliang, Lv, Huipeng, Zhou, Yang, Zheng, Xiaotong, Wu, Chen, Xu, Chen·2018·ACS Applied Materials & Interfaces

Abstract

Sandwich-like MXene/Fe 3 O 4 and C/TiO 2 /α-Fe two-dimensional (2D) nanocomposites were fabricated via in situ hydrothermal assembly of Fe 3 O 4 nanoparticles on MXene nanosheets and postannealing. The as-prepared sandwich-like MXene/Fe 3 O 4 nanocomposites contain uniformly distributed Fe 3 O 4 nanoparticles between the interlayers of the 2D MXene Ti 3 C 2 T x nanoflakes. The redox reaction, Ti 3 C 2 T x + Fe 3 O 4 → 3TiO 2 + 2C + 3Fe, has also been reported for the first time to transform the binary MXene/Fe 3 O 4 nanocomposites into ternary C/TiO 2 /α-Fe nanocomposites with the 2D structure maintained intact. Such a transition during postannealing gives rise to further enhanced electromagnetic wave absorption compared with that of the MXene/Fe 3 O 4 nanocomposites on top of the already improved performance of the MXene/Fe 3 O 4 compared with that of pristine MXene. The 2D C/TiO 2 /α-Fe nanocomposites exhibit effective absorption bandwidths of 3.3 and 3.5 GHz at thicknesses of 1 and 1.5 mm, respectively. This work offers a new route for fabricating novel electromagnetic wave absorbers, and the fine balance among lightweight, broad band, and small thickness of the C/TiO 2 /α-Fe nanocomposites makes them promising in the field of electromagnetic wave absorption.

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Metadata

Authors
Zhao, G., Lv, H., Zhou, Y., Zheng, X., Wu, C., & Xu, C.
Venue
ACS Applied Materials & Interfaces
Published
2018-11-13
Volume
10
Issue
49
Pages
42925-42932
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2900547507
Cited by
236
References
1
FWCI
6.33
Type
journal article
Language
en
Open access
closed

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