The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Carbazolic Porous Organic Framework as an Efficient, Metal-Free Visible-Light Photocatalyst for Organic Synthesis
Abstract
We report the visible-light-promoted photocatalytic activity of a highly porous carbazolic organic framework, Cz-POF-1, toward three prototypic organic transformations: net reductive dehalogenation of phenacyl bromide and its derivatives, net oxidative hydroxylation of arylboronic acids, and redox-neutral α-alkylation of aldehydes. We show that the extended π-conjugation in Cz-POF-1 enhances its visible light absorption, and the large porosity accelerates the reaction rate. For α-alkylation of aldehydes, Cz-POF-1 requires less strict reaction conditions and can be easily recovered and reused for up to 10 times. This work reveals a bright future for Cz-POFs as a new generation of metal-free photocatalysts for organic synthesis.
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Visible light photoredox catalysis: applications in organic synthesis
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Visible light photocatalysis as a greener approach to photochemical synthesis
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Solar Synthesis: Prospects in Visible Light Photocatalysis
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Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
Nicewicz, D. A., & MacMillan, D. W. C. (2008) · Science · doi:10.1126/science.1161976 · Cited by 2,489
Visible‐Light Photoredox Catalysis
Xuan, J., & Xiao, W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200223 · Cited by 2,262
Design and Preparation of Porous Polymers
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Conjugated microporous polymers: design, synthesis and application
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Conjugated Microporous Poly(aryleneethynylene) Networks
Jiang, J., Su, F., Trewin, A., Wood, C. D., Campbell, N. L., Niu, H., Dickinson, C., Ganin, A. Y., Rosseinsky, M. J., Khimyak, Y. Z., et al. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200701595 · Cited by 1,465
Cited by
Benzoxazole-Linked Ultrastable Covalent Organic Frameworks for Photocatalysis
Wei, P.-F., Qi, M.-Z., Wang, Z.-P., Ding, S.-Y., Yu, W., Liu, Q., Wang, L.-K., Wang, H.-Z., An, W.-K., & Wang, W. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00571 · Cited by 771
Conjugated polymers for visible-light-driven photocatalysis
Dai, C., & Liu, B. (2020) · Energy & Environmental Science · doi:10.1039/c9ee01935a · Cited by 687
Chen, F., Yang, Q., Wang, Y., Zhao, J., Wang, D., Li, X., Guo, Z., Wang, H., Deng, Y., Niu, C., et al. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.12.017 · Cited by 429
Porous organic polymers: a promising platform for efficient photocatalysis
Zhang, T., Xing, G., Chen, W., & Chen, L. (2020) · Materials Chemistry Frontiers · doi:10.1039/c9qm00633h · Cited by 420
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Gisbertz, S., & Pieber, B. (2020) · ChemPhotoChem · doi:10.1002/cptc.202000014 · Cited by 312
Metadata
- Authors
- Luo, J., Zhang, X., & Zhang, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-10
- Volume
- 5
- Issue
- 4
- Pages
- 2250-2254
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2071279459
- Cited by
- 255
- References
- 46
- FWCI
- 12.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Luo, J., Zhang, X., & Zhang, J. (2015). Carbazolic Porous Organic Framework as an Efficient, Metal-Free Visible-Light Photocatalyst for Organic Synthesis. ACS Catalysis. https://doi.org/10.1021/acscatal.5b00025
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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