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[Copper(phenanthroline)(bisisonitrile)]+-Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions

Knorn, Matthias, Rawner, Thomas, Czerwieniec, Rafał, Reiser, Oliver·2015·ACS Catalysis

Abstract

A series of heteroleptic [Cu(phenantroline)(bisisonitrile)] + -complexes was synthesized, and their structural, spectroscopic, and electrochemical properties were investigated. The new copper(I) complexes were employed as photoredox-catalysts in the visible-light-mediated atom transfer radical addition (ATRA). Especially, [Cu(dpp)(binc)]BF 4 ( 6a-BF 4 )(dpp = 2,9-diphenyl-1,10-phenanthroline; binc = bis(2-isocyanophenyl) phenylphosphonate) proved to be highly active owing to an enhanced excited-state lifetime compared to the commonly employed [Cu(dap) 2 ]Cl ( 1-Cl )(dap = 2,9-di( p -anisyl)-1,10-phenanthroline). Furthermore, the catalyst could be applied to allylation reactions with trimethylallylsilane under mild visible-light photoredox conditions.

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Metadata

Authors
Knorn, M., Rawner, T., Czerwieniec, R., & Reiser, O.
Venue
ACS Catalysis
Published
2015-08-06
Volume
5
Issue
9
Pages
5186-5193
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2512314237
Cited by
195
References
1
FWCI
10.79
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: [Copper(phenanthroline)(bisisonitrile)]+-Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions. https://app.cochat.ai/papers/10.1021/acscatal.5b01071
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Knorn, M., Rawner, T., Czerwieniec, R., & Reiser, O. (2015). [Copper(phenanthroline)(bisisonitrile)]+-Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions. ACS Catalysis. https://doi.org/10.1021/acscatal.5b01071

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