The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Encapsulating a Co(II) Molecular Photocatalyst in Metal–Organic Framework for Visible-Light-Driven H2 Production: Boosting Catalytic Efficiency via Spatial Charge Separation
Abstract
The photodriven H 2 generation from water splitting, providing a high-performance energy source, has been recognized to be a promising pathway for solar energy conversion. However, the efficient charge separation for photocatalysts remains a critical issue. In this work, we have rationally encapsulated a Co(II) molecular photcatalyst, [Co II (TPA)Cl][Cl] (TPA = tris(2-pyridylmethyl)amine), inside the cages of a metal–organic framework (MOF) photosensitizer, MIL-125-NH 2, for visible-light-driven H 2 production. This noble-metal-free composite photocatalyst facilitates the photoinduced charge transfer from MIL-125-NH 2 to the Co(II) complex and greatly improves the spatial charge separation, thus significantly boosting the photocatalytic efficiency of H 2 production. In addition, MIL-125-NH 2 behaves as a host matrix to achieve hetrogenization of the Co(II) complex, and thus, the composite can be well-recycled.
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Citations
Cites
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
Self-citation
Cited by
Catalysis and photocatalysis by metal organic frameworks
Dhakshinamoorthy, A., Li, Z., & Garcia, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00256h · Cited by 1,505
Self-citationMetal–organic frameworks as a platform for clean energy applications
Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Metal–Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting
Navalón, S., Dhakshinamoorthy, A., Álvaro, M., Ferrer, B., & García, H. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00460 · Cited by 538
Li, G., Zhao, S., Zhang, Y., & Tang, Z. (2018) · Advanced Materials · doi:10.1002/adma.201800702 · Cited by 521
Modified metal-organic frameworks as photocatalysts
Qiu, J., Zhang, X., Feng, Y., Zhang, X., Wang, H., & Yao, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.03.039 · Cited by 499
Metadata
- Authors
- Li, Z., Xiao, J.-D., & Jiang, H.-L.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-20
- Volume
- 6
- Issue
- 8
- Pages
- 5359-5365
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2471450577
- Cited by
- 232
- References
- 2
- FWCI
- 6.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Encapsulating a Co(II) Molecular Photocatalyst in Metal–Organic Framework for Visible-Light-Driven H2 Production: Boosting Catalytic Efficiency via Spatial Charge Separation. https://app.cochat.ai/papers/10.1021/acscatal.6b01293
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- Li, Z., Xiao, J.-D., & Jiang, H.-L. (2016). Encapsulating a Co(II) Molecular Photocatalyst in Metal–Organic Framework for Visible-Light-Driven H2 Production: Boosting Catalytic Efficiency via Spatial Charge Separation. ACS Catalysis. https://doi.org/10.1021/acscatal.6b01293
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