The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates
Abstract
Aryl phosphonates are functional groups frequently found in pharmaceutical and crop protection agents. For their synthesis via C–P bond formation typically transition-metal-catalyzed reactions are used. We report a visible-light photo-Arbuzov reaction as an efficient, mild, and metal-free alternative. Rhodamine 6G (Rh.6G) is used as the photocatalyst, generating aryl radicals under blue light. Coupling of the radicals with a wide range of trivalent phosphites gives aryl phosphonates in good to very good isolated yields. The mild reaction conditions allow the introduction of a phosphonate group into complex and sensitive pharmaceutically active molecules such as benzodiazepams and nicergoline by the activation of a carbon–halogen bond.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Speckmeier, E., Fischer, T. G., & Zeitler, K. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08933 · Cited by 771
Stache, E. E., Ertel, A. B., Rovis, T., & Doyle, A. G. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b03592 · Cited by 366
Zafar, Z., Yi, S., Li, J., Li, C., Zhu, Y., Zada, A., Yao, W., Liu, Z., & Yue, X. (2022) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12171 · Cited by 284
Xu, J., Cao, J., Wu, X., Wang, H., Yang, X., Tang, X., Toh, R. W., Zhou, R., Yeow, E. K. L., & Wu, J. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05994 · Cited by 280
Metadata
- Authors
- Shaikh, R. S., Düsel, S. J. S., & König, B.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-21
- Volume
- 6
- Issue
- 12
- Pages
- 8410-8414
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2550192427
- Cited by
- 188
- References
- 1
- FWCI
- 8.32
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates. https://app.cochat.ai/papers/10.1021/acscatal.6b02591
- The paper
- Shaikh, R. S., Düsel, S. J. S., & König, B. (2016). Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates. ACS Catalysis. https://doi.org/10.1021/acscatal.6b02591
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
