The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting
Abstract
A systematic structural elucidation of the near-surface active species of the two remarkably active nickel phosphides Ni 12 P 5 and Ni 2 P on the basis of extensive analytical, microscopic, and spectroscopic investigations is reported. The latter can serve as complementary efficient electrocatalysts in the hydrogen (HER) versus oxygen evolution reaction (OER) in alkaline media. In the OER Ni 12 P 5 shows enhanced performance over Ni 2 P due to the higher concentration of nickel in this phase, which enables the formation of an amorphous NiOOH/Ni(OH) 2 shell on a modified multiphase with a disordered phosphide/phosphite core. The situation is completely reversed in the HER, where Ni 2 P displayed a significant improvement in electrocatalytic activity over Ni 12 P 5 owing to a larger concentration of phosphide/phosphate species in the shell. Moreover, the efficiently combined use of the two nickel phosphide phases deposited on nickel foam in overall electrocatalytic water splitting is demonstrated by a strikingly low cell voltage and high stability with pronounced current density, and these catalysts could be an apt choice for applications in commercial alkaline water electrolysis.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257
Liu, P., & Rodriguez, J. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0540019 · Cited by 1,240
Kibsgaard, J., Tsai, C., Chan, K., Benck, J. D., Nørskov, J. K., Abild-Pedersen, F., & Jaramillo, T. F. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02179k · Cited by 979
Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502577 · Cited by 554
Cited by
Vij, V., Sultan, S., Harzandi, A. M., Meena, A., Tiwari, J. N., Lee, W.-G., Yoon, T., & Kim, K. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01800 · Cited by 1,252
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Self-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Self-citationPeng, X., Yan, Y., Jin, X., Huang, C., Jin, W., Gao, B., & Chu, P. K. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105234 · Cited by 450
Shi, Y., Li, M., Yu, Y., & Zhang, B. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02577a · Cited by 426
Metadata
- Authors
- Menezes, P. W., Indra, A., Das, C., Walter, C., Göbel, C., Gutkin, V., Schmeiβer, D., & Driess, M.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-29
- Volume
- 7
- Issue
- 1
- Pages
- 103-109
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2552766327
- Cited by
- 422
- References
- 9
- FWCI
- 10.28
- Type
- journal article
- Language
- en
- Open access
- closed
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- Menezes, P. W., Indra, A., Das, C., Walter, C., Göbel, C., Gutkin, V., Schmeiβer, D., & Driess, M. (2017). Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting. ACS Catalysis. https://doi.org/10.1021/acscatal.6b02666
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