The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Isolated Single-Atomic Ru Catalyst Bound on a Layered Double Hydroxide for Hydrogenation of CO2 to Formic Acid
Abstract
In order to achieve an economical CO 2 -mediated hydrogen energy cycle, the development of heterogeneous catalysts for CO 2 hydrogenation to formic acid is an urgent and challenging task. In this study, a stable and well-defined single-site Ru catalyst on the surface of a layered double hydroxide (LDH) in a basic medium is proven to be efficient for selective hydrogenation of CO 2 to formic acid under mild reaction conditions (2.0 MPa, 100 °C). The electron-donating ability of triads of basic hydroxyl ligands with a particular location is crucial for an active electron-rich Ru center. There is a strong correlation between catalytic activity and adjustable CO 2 adsorption capacity in the vicinity of the Ru center. Such electronic metal–support interactions and a CO 2 concentration effect result in a significant positive influence on the catalytic activity.
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Cites
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Cited by
Li, P., Wang, M., Duan, X., Zheng, L., Cheng, X., Zhang, Y., Kuang, Y., Li, Y., Ma, Q., Feng, Z., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09666-0 · Cited by 717
Zhang, J., Wu, X., Cheong, W.-C., Chen, W., Lin, R., Li, J., Zheng, L., Yan, W., Gu, L., Chen, C., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-03380-z · Cited by 354
Metadata
- Authors
- Mori, K., Taga, T., & Yamashita, H.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-03-31
- Volume
- 7
- Issue
- 5
- Pages
- 3147-3151
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2602503121
- Cited by
- 269
- References
- 2
- FWCI
- 7.94
- Type
- journal article
- Language
- en
- Open access
- closed
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