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Cited by 215

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Activity and Stability of Pt/IrO2 Bifunctional Materials as Catalysts for the Oxygen Evolution/Reduction Reactions

da Silva, Gabriel C., Fernandes, Mauro R., Ticianelli, Edson A.·2018·ACS Catalysis

Abstract

Pt/IrO 2 bifunctional catalysts synthesized with varying Pt:Ir ratios and characterized using several techniques, including energy dispersive X-ray spectroscopy, transmission electrons microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, were investigated for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in acid media. Three stability testing protocols are used to evaluate the catalysts stabilities, comprising electrode cycling in the ORR, OER, and ORR–OER potential ranges. Electrochemical results provide evidence that a Pt/IrO 2 1:9 material exhibits better balance between the OER and ORR mass activities and that cycling in the ORR-OER potential window is the most aggressive aging protocol for the Pt/IrO 2 materials. Identical location transmission electron microscopy is used to investigate the aging processes taking part in the Pt/IrO 2 catalysts. In addition to dissolution processes, particle coalescence, growth, and detachment are confirmed as responsible for the Pt/IrO 2 instability.

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Metadata

Authors
da Silva, G. C., Fernandes, M. R., & Ticianelli, E. A.
Venue
ACS Catalysis
Published
2018-02-06
Volume
8
Issue
3
Pages
2081-2092
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2786269203
Cited by
215
References
1
FWCI
6.22
Type
journal article
Language
en
Open access
closed

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