The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Boosting Photocatalytic Hydrogen Production of Porphyrinic MOFs: The Metal Location in Metalloporphyrin Matters
Abstract
Metal–organic frameworks (MOFs) have demonstrated great potentials toward catalysis, particularly in the establishment of structure–property relationships. Herein, an unusual OOP (out-of-plane) porphyrin-based MOF, synthesized by controlling the metal ion release with an unprecedented In(OH) 3 precursor, possesses high stability and exhibits unexpectedly high photocatalytic hydrogen production activity, far surpassing the isostructural in-plane porphyrin-based MOF counterparts. In the MOF structure, indium ions not only form indium–oxo chains but also metalate the porphyrin rings in situ, locating above the porphyrin plane instead of fitting in a coplanar fashion into the cavity and affording an unusual OOP porphyrin. Control experiments demonstrate that the OOP In(III) ions readily detach from the porphyrin rings under light excitation, avoiding the fast back electron transfer and thus greatly improving electron–hole separation efficiency and photocatalytic performance. To our knowledge, this is an unprecedented report on boosting MOF photocatalysis on the basis of special metalloporphyrin behavior.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
OLEX2 : a complete structure solution, refinement and analysis program
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., & Puschmann, H. (2009) · Journal of Applied Crystallography · doi:10.1107/s0021889808042726 · Cited by 32,811
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Single-crystal structure validation with the program PLATON
Spek, A. L. (2003) · Journal of Applied Crystallography · doi:10.1107/s0021889802022112 · Cited by 14,084
Heterogeneous photocatalyst materials for water splitting
Kudo, A., & Miseki, Y. (2009) · Chem. Soc. Rev. · doi:10.1039/b800489g · Cited by 10,585
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Metal–Organic Frameworks (MOFs)
Zhou, H.-C. “., & Kitagawa, S. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs90059f · Cited by 4,125
Metal–organic frameworks for artificial photosynthesis and photocatalysis
Zhang, T., & Lin, W. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00103f · Cited by 2,163
Feng, D., Gu, Z., Li, J., Jiang, H., Wei, Z., & Zhou, H. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204475 · Cited by 1,978
Self-citationFu, Y., Sun, D., Chen, Y., Huang, R., Ding, Z., Fu, X., & Li, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108357 · Cited by 1,741
Cited by
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Metal-organic frameworks for stimuli-responsive drug delivery
Wang, Y., Yan, J., Wen, N., Xiong, H., Cai, S., He, Q., Hu, Y., Peng, D., Liu, Z., & Liu, Y. (2020) · Biomaterials · doi:10.1016/j.biomaterials.2019.119619 · Cited by 665
Construction and application of base-stable MOFs: a critical review
Wang, K., Li, Y., Xie, L.-H., Li, X., & Li, J.-R. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00891a · Cited by 462
Porphyrins and phthalocyanines as biomimetic tools for photocatalytic H2production and CO2reduction
Nikoloudakis, E., López-Duarte, I., Charalambidis, G., Ladomenou, K., Ince, M., & Coutsolelos, A. G. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00183g · Cited by 369
Metadata
- Authors
- Leng, F., Liu, H., Ding, M., Lin, Q.-P., & Jiang, H.-L.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-04-13
- Volume
- 8
- Issue
- 5
- Pages
- 4583-4590
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2800851589
- Cited by
- 266
- References
- 46
- FWCI
- 8.59
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Boosting Photocatalytic Hydrogen Production of Porphyrinic MOFs: The Metal Location in Metalloporphyrin Matters. https://app.cochat.ai/papers/10.1021/acscatal.8b00764
- The paper
- Leng, F., Liu, H., Ding, M., Lin, Q.-P., & Jiang, H.-L. (2018). Boosting Photocatalytic Hydrogen Production of Porphyrinic MOFs: The Metal Location in Metalloporphyrin Matters. ACS Catalysis. https://doi.org/10.1021/acscatal.8b00764
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
