The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Catalytic Hydrogenation of CO2 to Isoparaffins over Fe-Based Multifunctional Catalysts
Abstract
Direct conversion of CO 2 into isoparaffins, ideal clean hydrocarbon fuel components, would be an eco-friendly way of mitigating CO 2 emissions and replacing fossil fuels. Herein, we realize a one-step high-yield synthesis of isoparaffins from CO 2 hydrogenation, catalyzed by a multifunctional Na–Fe 3 O 4 /HMCM-22 catalyst. A selectivity of 82% among hydrocarbons was achieved for C 4+ hydrocarbons, of which isoparaffins could account for 74%, while CO selectivity was as low as 17% at a CO 2 conversion of 26%. The high yield to isoparaffins was derived owing to well matching of three tandem reactions comprising reverse water–gas shift, C–C coupling and isomerization. Unique pore structure and appropriate Brønsted acid properties of HMCM-22 effectively suppressed aromatization, while promoting isomerization. Coke deposition inside the micropores of HMCM-22 causes the decline of isoparaffin yield without changing the total yield of heavy hydrocarbons. Both the physicochemical properties and catalytic performances of the catalysts could still keep their original levels after several reaction-regeneration cycles, indicating a promising potential application in the future commercialization process of CO 2 hydrogenation.
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Citations
Cites
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Cited by
Cui, W.-G., Zhang, G.-Y., Hu, T.-L., & Bu, X.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.02.001 · Cited by 406
Novel Heterogeneous Catalysts for CO2 Hydrogenation to Liquid Fuels
Gao, P., Zhang, L., Li, S., Zhou, Z., & Sun, Y. (2020) · ACS Central Science · doi:10.1021/acscentsci.0c00976 · Cited by 361
Advances in the Design of Heterogeneous Catalysts and Thermocatalytic Processes for CO2 Utilization
De, S., Dokania, A., Ramirez, A., & Gascon, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c04273 · Cited by 355
Applications of Zeolites to C1 Chemistry: Recent Advances, Challenges, and Opportunities
Zhang, Q., Yu, J., & Corma, A. (2020) · Advanced Materials · doi:10.1002/adma.202002927 · Cited by 316
Catalytic reduction of CO2into fuels and fine chemicals
Modak, A., Bhanja, P., Dutta, S., Chowdhury, B., & Bhaumik, A. (2020) · Green Chemistry · doi:10.1039/d0gc01092h · Cited by 267
Metadata
- Authors
- Wei, J., Yao, R., Ge, Q., Wen, Z., Ji, X., Fang, C., Zhang, J., Xu, H., & Sun, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-17
- Volume
- 8
- Issue
- 11
- Pages
- 9958-9967
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2892112811
- Cited by
- 214
- References
- 1
- FWCI
- 4.32
- Type
- journal article
- Language
- en
- Open access
- closed
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