Dynamic Nonlinear Effects in Asymmetric Catalysis
Abstract
For three decades, “conventional” nonlinear effects in asymmetric catalysis, commonly becoming apparent as a nonproportional relationship between the enantiomeric purity of the chiral catalyst and that of the chiral reaction product, have been extensively studied from both fundamental and practical perspectives and thoroughly reviewed. In contrast, this review is focused on dynamic nonlinear effects, with the catalyst systems exhibiting variation of enantioselectivity over the reaction course, caused by catalyst–product or catalyst–substrate interactions. Namely, such phenomena as asymmetric autoinduction, asymmetric autocatalysis, and asymmetric autoamplification are considered and the corresponding catalytic reactions are surveyed. Whenever available, data on the origins of the observed nonlinearities are presented. Several kinetic schemes, illustrating the nonlinear ee variation over the reaction course, are considered. Possible implications of dynamic nonlinear effects in asymmetric catalysis in the problem of biological homochirality on Earth are discussed briefly.
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Some mechanisms are known for increasing an existing enantiomeric excess, such as self-disproportionation of enantiomers, non-linear effects in asymmetric catalysis, and stereoselective polymerization.
“Some mechanisms are known for increasing an existing e.e., such as the self-disproportionation of enantiomers (SDE), 61 non-linear effects in asymmetric catalysis, 62,63 and stereoselective polymerization.64”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [63]
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Buhse, T., Cruz, J.-M., Noble-Terán, M. E., Hochberg, D., Ribó, J. M., Crusats, J., & Micheau, J.-C. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00819 · Cited by 189 · see citing works
Possible chemical and physical scenarios towards biological homochirality
Sallembien, Q., Bouteiller, L., Crassous, J., & Raynal, M. (2022) · Chemical Society Reviews · doi:10.1039/d1cs01179k · Cited by 186 · see citing works
- Authors
- Bryliakov, K. P.
- Affiliations
- Novosibirsk State University (RU)
- Corresponding author
- Bryliakov, Konstantin P.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-03
- Volume
- 9
- Issue
- 6
- Pages
- 5418-5438
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2943471335
- Cited by
- 32
- References
- 22
- Citations by year
- 2026: 3 · 2025: 6 · 2024: 3 · 2023: 6 · 2022: 5 · 2021: 5 · 2020: 3 · 2019: 1
- FWCI
- 1.37
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Catalysis (publishedVersion)
- Funders
- Russian Foundation for Basic Research (18-33-20078)
- Ministry of Science and Higher Education of Russia (AAAA-A17-117041710080-4)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Physical Sciences › Chemistry › Inorganic Chemistry › Asymmetric Hydrogenation and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Axial and Atropisomeric Chirality Synthesis
- Keywords
- asymmetric catalysis, asymmetric autocatalysis, enantioselectivity, catalyst-substrate interaction, enantiomeric excess, reaction kinetics
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