Revealing the Highly Catalytic Performance of Spinel CoMn2O4 for Toluene Oxidation: Involvement and Replenishment of Oxygen Species Using In Situ Designed-TP Techniques

Abstract

The catalytic oxidation of toluene to CO 2 and H 2 O over nanoflower spinel CoMn 2 O 4 synthesized by the oxalic acid sol–gel method has been investigated, and it demonstrates lower activation energy (35.5 kJ/mol) for toluene oxidation compared with that using the metal oxides (Co 3 O 4, MnO x, and Co 3 O 4 /MnO x ), which shows nearly 100% conversion of toluene at 220 °C in the presence or absence of water vapor (2.0 vol %). Compared with the metal oxides (Co 3 O 4 /MnO x, MnO x, and Co 3 O 4 ), the obtained spinel CoMn 2 O 4 has a larger surface area, rich cationic vacancy, and high mobility of oxygen species, which are the reasons for its high activity for toluene oxidation. The different oxygen species shows the different role in VOCs oxidation, and the in situ designed-TP techniques are conducted to investigate the involvement of surface lattice oxygen, bulk lattice oxygen, and gaseous oxygen in catalytic oxidation of toluene over the spinel CoMn 2 O 4 and Co 3 O 4 /MnO x catalysts. For spinel CoMn 2 O 4, the surface lattice oxygen is the reactive oxygen species, which first induces the catalytic reaction. Furthermore, the gaseous oxygen moves to the bulk phase lattice and then migrates to the surface to form the surface lattice oxygen, which is different from the mixed-metal oxides Co 3 O 4 /MnO x that dissociates and activates gaseous oxygen only on the surface of the catalyst and requires a higher temperature. In addition, it is found that the toluene oxidation occurs via the benzyl alcohol–benzoate–anhydride–acetate reaction pathway over spinel CoMn 2 O 4, and the conversion of the surface anhydride is the rate-controlling step, especially at 200–210 °C, which is also different from the mixed-metal oxides Co 3 O 4 /MnO x . These results could provide a considerable experimental basis for understanding the mechanism by which oxygen species participate in toluene oxidation.