The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Bimetallic Composition-Promoted Electrocatalytic Hydrodechlorination Reaction on Silver–Palladium Alloy Nanoparticles
Abstract
Studies of the electrocatalytic hydrodechlorination (EHDC) reaction using monodisperse AgPd nanoparticle (NP) model catalysts in the present work reveal the essential role of the catalytically inert Ag component in promoting bimetallic nanocatalyst’s activity for the conversion of 2,4-dichlorophenol (2,4-DCP) to phenol (P). The EHDC reaction rate, current efficiency, and product selectivity were systematically investigated, leading to the observation of a volcano-type activity dependence on the Ag content in bimetallic NPs. The combination of kinetics analyses and density functional theory calculations demonstrates that the balance of 2,4-DCP adsorption and P desorption is the dominant factor for EHDC efficiency rather than other processes (e.g., hydrogen adsorbent formation). The presence of Ag, if precisely controlled in the proper range, alleviates the overstrong adsorption of P, allowing for a much enhanced EHDC kinetics compared to single-component Pd. This work provides a deep understanding of the EHDC mechanism over bimetallic nanocatalysts and a facile approach to optimizing this important environmental electrocatalysis strategy.
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Citations
Cites
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
Stamenkovic, V. R., Mun, B. S., Arenz, M., Mayrhofer, K. J. J., Lucas, C. A., Wang, G., Ross, P. N., & Markovic, N. M. (2007) · Nature Materials · doi:10.1038/nmat1840 · Cited by 3,252
Strain-controlled electrocatalysis on multimetallic nanomaterials
Luo, M., & Guo, S. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.59 · Cited by 1,115
Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402
Self-citation
Cited by
Recent Progress on Rational Design of Bimetallic Pd Based Catalysts and Their Advanced Catalysis
Fan, J., Du, H., Zhao, Y., Wang, Q., Liu, Y., Li, D., & Feng, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03280 · Cited by 265
Metadata
- Authors
- Peng, Y., Cui, M., Zhang, Z., Shu, S., Shi, X., Brosnahan, J. T., Liu, C., Zhang, Y., Godbold, P., Zhang, X., Dong, F., Jiang, G., & Zhang, S.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-09-16
- Volume
- 9
- Issue
- 12
- Pages
- 10803-10811
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2973820273
- Cited by
- 186
- References
- 3
- FWCI
- 6.72
- Type
- journal article
- Language
- en
- Open access
- closed
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