The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
High-Performance MaZrOx (Ma = Cd, Ga) Solid-Solution Catalysts for CO2 Hydrogenation to Methanol
Open accessAbstract
Hydrogenation of CO 2 to methanol utilizing the hydrogen from renewable energy sources offers a promising way to reduce CO 2 emissions through the CO 2 utilization as a carbon source. However, it is a challenge to convert CO 2 to methanol with high activity and high methanol selectivity. Herein, we report a class of metal-oxide solid-solution catalysts: M a ZrO x (M a = Cd, Ga), which show a methanol selectivity up to 80% with the CO 2 single pass conversion reaching 4.3%–12.4% under the reaction conditions of H 2 /CO 2 = 3/1, 24 000 h –1, 5 MPa. Structural and electronic characterizations combined with denisty functional theory calculations suggest that the M a and Zr components in M a ZrO x (M a = Cd, Ga) solid-solution catalysts show a strong synergetic effect, which enhances the H 2 heterolytic dissociation and results in high activity and high methanol selectivity. The solid-solution catalyst with dual metal oxide components offers an approach for the selective hydrogenation of CO 2 to chemicals.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Cited by
Highlights and challenges in the selective reduction of carbon dioxide to methanol
Navarro-Jaén, S., Virginie, M., Bonin, J., Robert, M., Wojcieszak, R., & Khodakov, A. Y. (2021) · Nature Reviews Chemistry · doi:10.1038/s41570-021-00289-y · Cited by 647
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation
Zhao, H., Yu, R., Ma, S., Xu, K., Chen, Y., Jiang, K., Fang, Y., Zhu, C., Liu, X., Tang, Y., et al. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00840-0 · Cited by 628
Novel Heterogeneous Catalysts for CO2 Hydrogenation to Liquid Fuels
Gao, P., Zhang, L., Li, S., Zhou, Z., & Sun, Y. (2020) · ACS Central Science · doi:10.1021/acscentsci.0c00976 · Cited by 361
Feng, Z., Tang, C., Zhang, P., Li, K., Li, G., Wang, J., Feng, Z., & Li, C. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c02248 · Cited by 294
Self-citationHan, Z., Tang, C., Wang, J., Li, L., & Li, C. (2021) · Journal of Catalysis · doi:10.1016/j.jcat.2020.06.018 · Cited by 257
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Metadata
- Authors
- Wang, J., Tang, C., Li, G., Han, Z., Li, Z., Liu, H., Cheng, F., & Li, C.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-10-04
- Volume
- 9
- Issue
- 11
- Pages
- 10253-10259
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2978510442
- Cited by
- 269
- References
- 2
- FWCI
- 4.43
- Type
- journal article
- Language
- en
- Open access
- green
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