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Transient Voltammetry with Ultramicroelectrodes Reveals the Electron Transfer Kinetics of Lithium Metal Anodes
Abstract
Fully understanding the mechanism of lithium metal deposition is critical for the development of rechargeable lithium battery anodes. The heterogeneous electron transfer kinetics are an important aspect of lithium electrodeposition, but they have been difficult to measure and understand. Here, we use transient voltammetry with ultramicroelectrodes to explicitly investigate the electron transfer kinetics of lithium electrodeposition. The results deviate from the Butler–Volmer model of electrode kinetics; instead, a Marcus model accurately describes the electron transfer. Measuring the kinetics in a series of electrolytes shows the mechanism of lithium deposition under electron transfer control is consistent with the general framework of Marcus theory. Comparison of the transient voltammetry results to electrochemical impedance spectra provides a strategy for understanding how the interplay of the electron transfer and mass transport resistances affect the morphology of lithium.
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Citations
Cites
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Cited by
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries
Krauskopf, T., Richter, F. H., Zeier, W. G., & Janek, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00431 · Cited by 892
Lithium Batteries and the Solid Electrolyte Interphase (SEI)—Progress and Outlook
Adenusi, H., Chass, G. A., Passerini, S., Tian, K. V., & Chen, G. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203307 · Cited by 830
Solid electrolyte interphases in lithium metal batteries
Jagger, B., & Pasta, M. (2023) · Joule · doi:10.1016/j.joule.2023.08.007 · Cited by 592
Corrosion of lithium metal anodes during calendar ageing and its microscopic origins
Boyle, D. T., Huang, W., Wang, H., Li, Y., Chen, H., Yu, Z., Zhang, W., Bao, Z., & Cui, Y. (2021) · Nature Energy · doi:10.1038/s41560-021-00787-9 · Cited by 334
Self-citationInsights into the deposition chemistry of Li ions in nonaqueous electrolyte for stable Li anodes
Wang, Z., Sun, Z., Li, J., Shi, Y., Sun, C., An, B., Cheng, H.-M., & Li, F. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01017k · Cited by 268
Metadata
- Authors
- Boyle, D. T., Kong, X., Pei, A., Rudnicki, P. E., Shi, F., Huang, W., Bao, Z., Qin, J., & Cui, Y.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-02-03
- Volume
- 5
- Issue
- 3
- Pages
- 701-709
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W3004593247
- Cited by
- 197
- References
- 1
- FWCI
- 7.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Boyle, D. T., Kong, X., Pei, A., Rudnicki, P. E., Shi, F., Huang, W., Bao, Z., Qin, J., & Cui, Y. (2020). Transient Voltammetry with Ultramicroelectrodes Reveals the Electron Transfer Kinetics of Lithium Metal Anodes. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.0c00031
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