The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Ultrastable Anode Interface Achieved by Fluorinating Electrolytes for All-Solid-State Li Metal Batteries
Abstract
All-solid-state Li metal batteries (ASSLMBs) have attracted significant attention because of their high energy density and improved safety. However, the poor stability at the Li anode/solid-state electrolyte (SSE) interface is a long-standing problem that limits the current density and capacity, thus hindering the practical application of ASSLMBs. Herein, fluorination of an Argyrodite Li 6 PS 5 Cl (LPSCl) sulfide electrolyte is proposed to enhance the interfacial stability toward the Li metal anode. Because of the condensed and highly fluorinated interface that forms in situ with a self-healing essence, the Li metal symmetric cell employing the fluorinated LPSCl SSE enables ultrastable Li plating/stripping over 250 h at a superhigh current density of 6.37 mA cm –2 and a cutoff capacity of 5 mAh cm –2 . Furthermore, the Li metal treated by the fluorinated LPSCl SSE is demonstrated to deliver good durability and rate capability in full cells. Fluorinating sulfide electrolytes provides a new strategy for realizing high-performance ASSLMBs.
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Cites
A lithium superionic conductor
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Self-citationHigh-power all-solid-state batteries using sulfide superionic conductors
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High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes
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Self-citationChen, R., Li, Q., Yu, X., Chen, L., & Li, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00268 · Cited by 1,678
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Cited by
Wang, C., Liang, J., Zhao, Y., Zheng, M., Li, X., & Sun, X. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00551k · Cited by 489
Self-citationFluorination in advanced battery design
Wang, Y., Wu, Z., Azad, F. M., Zhu, Y., Wang, L., Hawker, C. J., Whittaker, A. K., Forsyth, M., & Zhang, C. (2023) · Nature Reviews Materials · doi:10.1038/s41578-023-00623-4 · Cited by 333
Metadata
- Authors
- Zhao, F., Sun, Q., Yu, C., Zhang, S., Adair, K., Wang, S., Liu, Y., Zhao, Y., Liang, J., Wang, C., Li, X., Li, X., Xia, W., Li, R., Huang, H., Zhang, L., Zhao, S., Lu, S., & Sun, X.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-05
- Volume
- 5
- Issue
- 4
- Pages
- 1035-1043
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W3009632230
- Cited by
- 294
- References
- 32
- FWCI
- 14.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, F., Sun, Q., Yu, C., Zhang, S., Adair, K., Wang, S., Liu, Y., Zhao, Y., Liang, J., Wang, C., Li, X., Li, X., Xia, W., Li, R., Huang, H., Zhang, L., Zhao, S., Lu, S., & Sun, X. (2020). Ultrastable Anode Interface Achieved by Fluorinating Electrolytes for All-Solid-State Li Metal Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.0c00207
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