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Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance
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Abstract This Perspective outlines basic structural and optical properties of lead halide perovskite colloidal nanocrystals, highlighting differences and similarities between them and conventional II–VI and III–V semiconductor quantum dots. A detailed insight into two important issues inherent to lead halide perovskite nanocrystals then follows, namely, the advantages of defect tolerance and the necessity to improve their stability in environmental conditions. The defect tolerance of lead halide perovskites offers an impetus to search for similar attributes in other related heavy metal-free compounds. We discuss the origins of the significantly blue-shifted emission from CsPbBr3 nanocrystals and the synthetic strategies toward fabrication of stable perovskite nanocrystal materials with emission in the red and infrared parts of the optical spectrum, which are related to fabrication of mixed cation compounds guided by Goldschmidt tolerance factor considerations. We conclude with the view on perspectives of use of the colloidal perovskite nanocrystals for applications in backlighting of liquid-crystal TV displays.
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Cited by
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Akkerman, Q. A., Rainò, G., Kovalenko, M. V., & Manna, L. (2018) · Nature Materials · doi:10.1038/s41563-018-0018-4 · Cited by 2,287
Self-citationPerovskite synthesis, properties and their related biochemical and industrial application
Assirey, E. A. R. (2019) · Saudi Pharmaceutical Journal · doi:10.1016/j.jsps.2019.05.003 · Cited by 445
Achieving Near-Unity Photoluminescence Efficiency for Blue-Violet-Emitting Perovskite Nanocrystals
Mondal, N., De, A., & Samanta, A. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01909 · Cited by 435
Bi, C., Wang, S., Li, Q., Kershaw, S. V., Tian, J., & Rogach, A. L. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b00290 · Cited by 367
Self-citationAdvanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications
Zhou, K., Qi, B., Liu, Z., Wang, X., Sun, Y., & Zhang, L. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202411671 · Cited by 228
Metadata
- Authors
- Huang, H., Bodnarchuk, M. I., Kershaw, S. V., Kovalenko, M. V., & Rogach, A. L.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-28
- Volume
- 2
- Issue
- 9
- Pages
- 2071-2083
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2744182579
- Cited by
- 1,236
- References
- 0
- FWCI
- 46.99
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Huang, H., Bodnarchuk, M. I., Kershaw, S. V., Kovalenko, M. V., & Rogach, A. L. (2017). Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.7b00547
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