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Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr

Open access
Palazon, Francisco, Urso, Carmine, De Trizio, Luca, Akkerman, Quinten, Marras, Sergio, Locardi, Federico, Nelli, Ilaria, Ferretti, Maurizio, Prato, Mirko, Manna, Liberato·2017·ACS Energy Letters

Abstract

Abstract Perovskite-related Cs4PbBr6 nanocrystals present a “zero-dimensional” crystalline structure where adjacent [PbBr6]4– octahedra do not share any corners. We show in this work that these nanocrystals can be converted into “three-dimensional” CsPbBr3 perovskites by extraction of CsBr. This conversion drastically changes the optoelectronic properties of the nanocrystals that become highly photoluminescent. The extraction of CsBr can be achieved either by thermal annealing (physical approach) or by chemical reaction with Prussian Blue (chemical approach). The former approach can be simply carried out on a dried film without addition of any chemicals but does not yield a full transformation. Instead, reaction with Prussian Blue in solution achieves a full transformation into the perovskite phase. This transformation was also verified on the iodide counterpart (Cs4PbI6).

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Metadata

Authors
Palazon, F., Urso, C., De Trizio, L., Akkerman, Q., Marras, S., Locardi, F., Nelli, I., Ferretti, M., Prato, M., & Manna, L.
Venue
ACS Energy Letters
Published
2017-09-25
Volume
2
Issue
10
Pages
2445-2448
ISSN
2380-8195 (ISSN-L)
OpenAlex
W2755409624
Cited by
213
References
2
FWCI
11.08
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr. https://app.cochat.ai/papers/10.1021/acsenergylett.7b00842
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Palazon, F., Urso, C., De Trizio, L., Akkerman, Q., Marras, S., Locardi, F., Nelli, I., Ferretti, M., Prato, M., & Manna, L. (2017). Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.7b00842

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