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Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr
Open accessAbstract
Abstract Perovskite-related Cs4PbBr6 nanocrystals present a “zero-dimensional” crystalline structure where adjacent [PbBr6]4– octahedra do not share any corners. We show in this work that these nanocrystals can be converted into “three-dimensional” CsPbBr3 perovskites by extraction of CsBr. This conversion drastically changes the optoelectronic properties of the nanocrystals that become highly photoluminescent. The extraction of CsBr can be achieved either by thermal annealing (physical approach) or by chemical reaction with Prussian Blue (chemical approach). The former approach can be simply carried out on a dried film without addition of any chemicals but does not yield a full transformation. Instead, reaction with Prussian Blue in solution achieves a full transformation into the perovskite phase. This transformation was also verified on the iodide counterpart (Cs4PbI6).
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
Akkerman, Q. A., Gandini, M., Di Stasio, F., Rastogi, P., Palazon, F., Bertoni, G., Ball, J. M., Prato, M., Petrozza, A., & Manna, L. (2016) · Nature Energy · doi:10.1038/nenergy.2016.194 · Cited by 721
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Cited by
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Quan, L. N., Rand, B. P., Friend, R. H., Mhaisalkar, S. G., Lee, T.-W., & Sargent, E. H. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00107 · Cited by 983
Cao, F., Yu, D., Ma, W., Xu, X., Cai, B., Yang, Y. M., Liu, S., He, L., Ke, Y., Lan, S., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b06114 · Cited by 322
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Yu, X., Wu, L., Yang, D., Cao, M., Fan, X., Lin, H., Zhong, Q., Xu, Y., & Zhang, Q. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202005120 · Cited by 281
Zero-Dimensional Cesium Lead Halides: History, Properties, and Challenges
Akkerman, Q. A., Abdelhady, A. L., & Manna, L. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00572 · Cited by 258
Self-citationUltrasensitive turn-on luminescence humidity sensor based on a perovskite/zeolite composite
Gao, Y.-J., Romolini, G., Huang, H., Jin, H., Saha, R. A., Ghosh, B., De Ras, M., Wang, C., Steele, J. A., Debroye, E., et al. (2022) · Journal of Materials Chemistry C · doi:10.1039/d2tc02498e · Cited by 32
Metadata
- Authors
- Palazon, F., Urso, C., De Trizio, L., Akkerman, Q., Marras, S., Locardi, F., Nelli, I., Ferretti, M., Prato, M., & Manna, L.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-09-25
- Volume
- 2
- Issue
- 10
- Pages
- 2445-2448
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2755409624
- Cited by
- 213
- References
- 2
- FWCI
- 11.08
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Palazon, F., Urso, C., De Trizio, L., Akkerman, Q., Marras, S., Locardi, F., Nelli, I., Ferretti, M., Prato, M., & Manna, L. (2017). Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.7b00842
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