The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Layered MgxV2O5·n H2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
Open accessAbstract
The performance of chemically intercalated V 2 O 5 was found to strongly depend on the interlayer spacing, which is related to the radius of hydrated metal ion, which can be readily tuned by using different intercalated metals. We report a layered Mg 2+ -intercalated V 2 O 5 as the cathode material for aqueous ZIBs. The large radius of hydrated Mg 2+ (∼4.3 Å, compared with 3.8 Å of commonly used Li + ) results in an interlayer spacing as large as 13.4 Å (against 11.07 Å for Li + -intercalated V 2 O 5 ), which allows efficient Zn 2+ (de)insertion. As a result, the obtained porous Mg 0.34 V 2 O 5 ·0.84H 2 O cathodes work in a wide potential window of 0.1 to 1.8 V versus Zn 2+ /Zn, and can deliver high capacities of 353 and 264 mA h g –1 at current densities of 100 and 1000 mA g –1, respectively, along with long-term durability. Furthermore, the reversible Zn 2+ (de)intercalation reaction mechanism is confirmed by multiple characterizations methods.
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Metadata
- Authors
- Ming, F., Liang, H., Lei, Y., Kandambeth, S., Eddaoudi, M., & Alshareef, H. N.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-28
- Volume
- 3
- Issue
- 10
- Pages
- 2602-2609
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2893067879
- Cited by
- 783
- References
- 40
- FWCI
- 31.80
- Type
- journal article
- Language
- en
- Open access
- green
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- Ming, F., Liang, H., Lei, Y., Kandambeth, S., Eddaoudi, M., & Alshareef, H. N. (2018). Layered MgxV2O5·n H2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b01423
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