The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries
Abstract
Safe lithium (Li) metal batteries have been plagued by dendrite growth due to a heterogeneous solid electrolyte interphases (SEI) on the Li metal anode. Modulating the solvation sheath of Li ions enhances the uniformity and stability of SEI significantly. However, anion regulation in the solvation sheath for constructing stable SEI is rarely touched. Herein, the solvation structure of original bis(fluorosulfonyl)imide (FSI – ) anions in the solvation sheath is altered by introduction of other anions, promoting the complete decomposition of FSI – and forming a stable SEI on the Li metal anode. Moreover, both the oxidation stability window of the electrolyte and current collector protection were enhanced. Furthermore, the components and structure of the solvation sheath were disclosed by combining 17 O nuclear magnetic resonance and molecular dynamics simulations. This work provides fresh insight into the interrelation among various anions on regulating the solvation sheath of Li ions and demonstrates guidance in rationally designing electrolytes for stable and safe Li metal batteries.
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Citations
Cites
Issues and challenges facing rechargeable lithium batteries
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Challenges for Rechargeable Li Batteries
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Self-citationElectrolytes and Interphases in Li-Ion Batteries and Beyond
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“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
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Cited by
Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature
Holoubek, J., Liu, H., Wu, Z., Yin, Y., Xing, X., Cai, G., Yu, S., Zhou, H., Pascal, T. A., Chen, Z., et al. (2021) · Nature Energy · doi:10.1038/s41560-021-00783-z · Cited by 851
Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries
Cheng, H., Sun, Q., Li, L., Zou, Y., Wang, Y., Cai, T., Zhao, F., Liu, G., Ma, Z., Wahyudi, W., et al. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02425 · Cited by 640
A Review of Solid Electrolyte Interphase (SEI) and Dendrite Formation in Lithium Batteries
Li, B., Chao, Y., Li, M., Xiao, Y., Li, R., Yang, K., Cui, X., Xu, G., Li, L., Yang, C., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00147-5 · Cited by 406
Self-citationCritical effects of electrolyte recipes for Li and Na metal batteries
Zheng, X., Huang, L., Ye, X., Zhang, J., Min, F., Luo, W., & Huang, Y. (2021) · Chem · doi:10.1016/j.chempr.2021.02.025 · Cited by 367
Lithium Metal Batteries Enabled by Synergetic Additives in Commercial Carbonate Electrolytes
Piao, N., Liu, S., Zhang, B., Ji, X., Fan, X., Wang, L., Wang, P.-F., Jin, T., Liou, S.-C., Yang, H., et al. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00365 · Cited by 355
Metadata
- Authors
- Zhang, X.-Q., Chen, X., Hou, L.-P., Li, B.-Q., Cheng, X.-B., Huang, J.-Q., & Zhang, Q.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-07
- Volume
- 4
- Issue
- 2
- Pages
- 411-416
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2910865293
- Cited by
- 485
- References
- 40
- FWCI
- 19.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, X.-Q., Chen, X., Hou, L.-P., Li, B.-Q., Cheng, X.-B., Huang, J.-Q., & Zhang, Q. (2019). Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b02376
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