The DOI matches its Crossref record; 38 of the 39 references it cites were found in a registry or an index.
Heteroatom-Doped Transition Metal Electrocatalysts for Hydrogen Evolution Reaction
Abstract
Developing efficient and low-cost electrocatalysts for the hydrogen evolution reaction (HER) is important for clean energy systems. Non-noble transition metals are the most promising candidates for replacement of conventional Pt group catalysts for the HER. However, most non-noble metals show poor HER activity due to their intrinsic electronic structures. Herein, we use a multifaceted heteroatom doping method (nitrogen, sulfur, and phosphorus) to directly and continuously fine-tune the electronic structure and HER activity of non-noble metals without changing their chemical composition. As a proof-of-concept, a nitrogen and phosphorus dual-doped Ni catalyst is explored by precisely manipulating doping modes, revealing the best HER performance among all doped Ni catalysts tested. The doping-induced charge redistribution in the Ni metal significantly influences its catalytic performance for the HER in alkaline media, which is confirmed by merging theoretical calculation with synchrotron-based spectroscopy. The principle that can bridge the doping modes and HER activity of the doped catalysts is built with a volcano relationship.
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Metadata
- Authors
- Jin, H., Liu, X., Chen, S., Vasileff, A., Li, L., Jiao, Y., Song, L., Zheng, Y., & Qiao, S.-Z.
- Affiliations
- The University of Adelaide (AU)
- University of Science and Technology of China (CN)
- Corresponding author
- Zheng, Yao
- Qiao, Shi-Zhang
- ORCID
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-02-26
- Volume
- 4
- Issue
- 4
- Pages
- 805-810
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2916738214
- Cited by
- 469
- References
- 39
- Citations by year
- 2026: 39 · 2025: 57 · 2024: 70 · 2023: 76 · 2022: 65 · 2021: 64 · 2020: 67 · 2019: 31
- FWCI
- 12.07
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Energy Letters (publishedVersion)
- Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
- Funders
- Australian Research Council (DP160104866, DE160101163, FL170100154)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- hydrogen evolution reaction, heteroatom doping, non-noble metal electrocatalysts, nickel catalysts, electronic structure modulation, charge redistribution, alkaline water electrolysis, volcano relationship, low-cost hydrogen production
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