Cited by 182Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsLayered Double Hydroxides Synthesis and Applications

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Ir–O–V Catalytic Group in Ir-Doped NiV(OH)2 for Overall Water Splitting

Li, Shuang, Xi, Cong, Jin, Yong-Zhen, Wu, Deyao, Wang, Jia-Qi, Liu, Tao, Wang, Hai-Bin, Dong, Cun-Ku, Liu, Hui, Kulinich, Sergei A., Du, Xi-Wen·2019·ACS Energy Letters

DOI 10.1021/acsenergylett.9b01252

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Abstract

Bifunctional electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are very crucial for converting water into clean fuel through overall water splitting. Here, we report on a bifunctional catalyst based on Ir-doped NiV layered double hydroxide with Ir–O–V catalytic groups on which water dissociation, HER, and OER occur on Ir, bridge O, and V atoms, respectively. Interestingly, the dopant Ir ions were found to play a triple role: (i) serve as catalytic sites for water dissociation, (ii) reduce charge density on adjacent bridge oxygen, thus facilitating HER there, and (iii) increase charge density on V ions, which in turn boosts OER. As a result, the catalyst achieves an ultralow applied voltage for overall water splitting (1.49 V @ 10 mA cm –2 ) and beats the noble metallic couple Pt/C and Ir/C with its value of 1.60 V @ 10 mA cm –2 .

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See all 182

Authors: Li, S., Xi, C., Jin, Y.-Z., Wu, D., Wang, J.-Q., Liu, T., Wang, H.-B., Dong, C.-K., Liu, H., Kulinich, S. A., & Du, X.-W.
Affiliations: Tianjin University (CN)
Institute of New Energy Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
Tokai University (JP)
Corresponding author: Liu, Hui
Kulinich, Sergei A.
Du, Xi-Wen
ORCID: Li, Shuang
Xi, Cong
Liu, Tao
Dong, Cun-Ku
Liu, Hui
Kulinich, Sergei A.
Du, Xi-Wen
Venue: ACS Energy Letters
Publisher: American Chemical Society (ACS)
Published: 2019-07-03
Volume: 4
Issue: 8
Pages: 1823-1829
ISSN: 2380-8195 (ISSN-L)
DOI: 10.1021/acsenergylett.9b01252
OpenAlex: W2955277063
Cited by: 182
References: 40
Citations by year: 2026: 5 · 2025: 17 · 2024: 24 · 2023: 35 · 2022: 36 · 2021: 38 · 2020: 24 · 2019: 3
FWCI: 5.37
Type: journal article
Language: en
Open access: closed
Licence: doi.org/10.15223/policy-029 (stm-asf)
doi.org/10.15223/policy-037 (stm-asf)
doi.org/10.15223/policy-045 (stm-asf)
Locations: ACS Energy Letters (publishedVersion)
Funders: National Natural Science Foundation of China (51671141, 51471115, 51871160)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
Keywords: overall water splitting, bifunctional electrocatalysts, hydrogen evolution reaction, oxygen evolution reaction, iridium doping, water dissociation, charge density, bridging oxygen, low overpotential

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Ir–O–V Catalytic Group in Ir-Doped NiV(OH)2 for Overall Water Splitting

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