“Fast-Charging” Anode Materials for Lithium-Ion Batteries from Perspective of Ion Diffusion in Crystal Structure

Abstract

"Fast-charging" lithium-ion batteries have gained a multitude of attention in recent years since they could be applied to energy storage areas like electric vehicles, grids, and subsea operations. Unfortunately, the excellent energy density could fail to sustain optimally while lithium-ion batteries are exposed to fast-charging conditions. In actuality, the crystal structure of electrode materials represents the critical factor for influencing the electrode performance. Accordingly, employing anode materials with low diffusion barrier could improve the "fast-charging" performance of the lithium-ion battery. In this Review, first, the "fast-charging" principle of lithium-ion battery and ion diffusion path in the crystal are briefly outlined. Next, the application prospects of "fast-charging" anode materials with various crystal structures are evaluated to search "fast-charging" anode materials with stable, safe, and long lifespan, solving the remaining challenges associated with high power and high safety. Finally, summarizing recent research advances for typical "fast-charging" anode materials, including preparation methods for advanced morphologies and the latest techniques for ameliorating performance. Furthermore, an outlook is given on the ongoing breakthroughs for "fast-charging" anode materials of lithium-ion batteries. Intercalated materials (niobium-based, carbon-based, titanium-based, vanadium-based) with favorable cycling stability are predominantly limited by undesired electronic conductivity and theoretical specific capacity. Accordingly, addressing the electrical conductivity of these materials constitutes an effective trend for realizing fast-charging. The conversion-type transition metal oxide and phosphorus-based materials with high theoretical specific capacity typically undergoes significant volume variation during charging and discharging. Consequently, alleviating the volume expansion could significantly fulfill the application of these materials in fast-charging batteries.