The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Enhancement Factors: A Central Concept during 50 Years of Surface-Enhanced Raman Spectroscopy
Abstract
In this Perspective, we provide an overview of the core concepts around surface-enhanced Raman spectroscopy (SERS) enhancement factors (EFs), including both theoretical and experimental considerations: EF definitions, the distinction between maximum and average EFs, EF distribution and hot-spot localization, EF measurement and its order of magnitude. We then highlight some of the current challenges in this field, focusing on a selection of topics that we feel are both topical and important: analyte-capture onto a SERS substrate, surface-enhanced resonant Raman scattering, orientation/tensorial effects, and nonradiative effects. We hope this Perspective can provide a platform to reflect on the past 50 years of SERS and its future.
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Cites
Raman spectra of pyridine adsorbed at a silver electrode
Fleischmann, M., Hendra, P. J., & McQuillan, A. J. (1974) · Chemical Physics Letters · doi:10.1016/0009-2614(74)85388-1 · Cited by 7,172
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Non-plasmonic nanoantennas for surface enhanced spectroscopies with ultra-low heat conversion
Caldarola, M., Albella, P., Cortés, E., Rahmani, M., Roschuk, T., Grinblat, G., Oulton, R. F., Bragas, A. V., & Maier, S. A. (2015) · Nature Communications · doi:10.1038/ncomms8915 · Cited by 520
Cited by
Surface-enhanced Raman spectroscopy: a half-century historical perspective
Yi, J., You, E.-M., Hu, R., Wu, D.-Y., Liu, G.-K., Yang, Z.-L., Zhang, H., Gu, Y., Wang, Y.-H., Wang, X., et al. (2025) · Chemical Society Reviews · doi:10.1039/d4cs00883a · Cited by 382
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Metadata
- Authors
- Le Ru, E. C., & Auguié, B.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2024-03-26
- Volume
- 18
- Issue
- 14
- Pages
- 9773-9783
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W4393200053
- Cited by
- 184
- References
- 3
- FWCI
- 14.21
- Type
- journal article
- Language
- en
- Open access
- closed
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