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Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films
Open accessAbstract
Two-dimensional covalent organic frameworks (2D COFs) are ideally suited for organizing redox-active subunits into periodic, permanently porous polymer networks of interest for pseudocapacitive energy storage. Here we describe a method for synthesizing crystalline, oriented thin films of a redox-active 2D COF on Au working electrodes. The thickness of the COF film was controlled by varying the initial monomer concentration. A large percentage (80-99%) of the anthraquinone groups are electrochemically accessible in films thinner than 200 nm, an order of magnitude improvement over the same COF prepared as a randomly oriented microcrystalline powder. As a result, electrodes functionalized with oriented COF films exhibit a 400% increase in capacitance scaled to electrode area as compared to those functionalized with the randomly oriented COF powder. These results demonstrate the promise of redox-active COFs for electrical energy storage and highlight the importance of controlling morphology for optimal performance.
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Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
Xu, Y., Sheng, K., Li, C., & Shi, G. (2010) · ACS Nano · doi:10.1021/nn101187z · Cited by 3,251
Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Mitra, S., Sasmal, H. S., Kundu, T., Kandambeth, S., Illath, K., Díaz Díaz, D., & Banerjee, R. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00925 · Cited by 587
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Metadata
- Authors
- DeBlase, C. R., Hernández-Burgos, K., Silberstein, K. E., Rodríguez-Calero, G. G., Bisbey, R. P., Abruña, H. D., & Dichtel, W. R.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-17
- Volume
- 9
- Issue
- 3
- Pages
- 3178-3183
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2327311573
- Cited by
- 381
- References
- 1
- FWCI
- 14.79
- Type
- journal article
- Language
- en
- Open access
- green
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- DeBlase, C. R., Hernández-Burgos, K., Silberstein, K. E., Rodríguez-Calero, G. G., Bisbey, R. P., Abruña, H. D., & Dichtel, W. R. (2015). Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films. ACS Nano. https://doi.org/10.1021/acsnano.5b00184
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