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Cited by 226

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Three-Dimensional Hierarchical Reduced Graphene Oxide/Tellurium Nanowires: A High-Performance Freestanding Cathode for Li–Te Batteries

He, Jiarui, Chen, Yuanfu, Lv, Weiqiang, Wen, Kechun, Wang, Zegao, Zhang, Wanli, Li, Yanrong, Qin, Wu, He, Weidong·2016·ACS Nano

Abstract

Three-dimensional aerogel with ultrathin tellurium nanowires (TeNWs) wrapped homogeneously by reduced graphene oxide (rGO) is realized via a facile hydrothermal method. Featured with high conductivity and large flexibility, the rGO constructs a conductive three-dimensional (3D) backbone with rich porosity and leads to a free-standing, binder-free cathode for lithium-tellurium (Li-Te) batteries with excellent electrochemical performances. The cathode shows a high initial capacity of 2611 mAh cm(-3) at 0.2 C, a high retention of 88% after 200 cycles, and a high-rate capacity of 1083 mAh cm(-3) at 10 C. In particular, the 3D aerogel cathode delivers a capacity of 1685 mAh cm(-3) at 1 C after 500 cycles, showing pronounced long-cycle performance at high current density. The performances are attributed to the well-defined flexible 3D architecture with high porosity and conductivity network, which offers highly efficient channels for electron transfer and ionic diffusion while compromising volume expansion of Te in charge/discharge. Owing to such advantageous properties, the reported 3D rGO/tellurium nanowire (3DGT) aerogel presents promising application potentials as a high-performance cathode for Li-Te batteries.

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Metadata

Authors
He, J., Chen, Y., Lv, W., Wen, K., Wang, Z., Zhang, W., Li, Y., Qin, W., & He, W.
Venue
ACS Nano
Published
2016-08-26
Volume
10
Issue
9
Pages
8837-8842
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2507598796
Cited by
226
References
1
FWCI
16.31
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Three-Dimensional Hierarchical Reduced Graphene Oxide/Tellurium Nanowires: A High-Performance Freestanding Cathode for Li–Te Batteries. https://app.cochat.ai/papers/10.1021/acsnano.6b04622
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He, J., Chen, Y., Lv, W., Wen, K., Wang, Z., Zhang, W., Li, Y., Qin, W., & He, W. (2016). Three-Dimensional Hierarchical Reduced Graphene Oxide/Tellurium Nanowires: A High-Performance Freestanding Cathode for Li–Te Batteries. ACS Nano. https://doi.org/10.1021/acsnano.6b04622

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