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Cited by 67Perovskite Materials and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsQuantum Dots Synthesis And Properties

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Metal/Covalent Organic Framework Encapsulated Lead-Free Halide Perovskite Hybrid Nanocatalysts: Multifunctional Applications, Design, Recent Trends, Challenges, and Prospects

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Altaf, Anam, Khan, Iltaf, Khan, Aftab, Sadiq, Samreen, Humayun, Muhammad, Khan, Shoaib, Zaman, Saeed, Khan, Abbas, Abumousa, Rasha A., Bououdina, Mohamed·2024·ACS Omega
DOI 10.1021/acsomega.4c04532PMC PMC11325423
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Abstract

High Resolution Image Download MS PowerPoint Slide Perovskites are bringing revolutionization in a various fields due to their exceptional properties and crystalline structure. Most specifically, halide perovskites (HPs), lead-free halide perovskites (LFHPs), and halide perovskite quantum dots (HPs QDs) are becoming hotspots due to their unique optoelectronic properties, low cost, and simple processing. HPs QDs, in particular, have excellent photovoltaic and optoelectronic applications because of their tunable emission, high photoluminescence quantum yield (PLQY), effective charge separation, and low cost. However, practical applications of the HPs QDs family have some limitations such as degradation, instability, and deep trap states within the bandgap, structural inflexibility, scalability, inconsistent reproducibility, and environmental concerns, which can be covered by encapsulating HPs QDs into porous materials like metal–organic frameworks (MOFs) or covalent–organic frameworks (COFs) that offer protection, prevention of aggregation, tunable optical properties, flexibility in structure, enhanced biocompatibility, improved stability under harsh conditions, consistency in production quality, and efficient charge separation. These advantages of MOFs-COFs help HPs QDs harness their full potential for various applications. This review mainly consists of three parts. The first portion discusses the perovskites, halide perovskites, lead-free perovskites, and halide perovskite quantum dots. In the second portion, we explore MOFs and COFs. In the third portion, particular emphasis is given to a thorough evaluation of the development of HPs QDs@MOFs-COFs based materials for comprehensive investigations for next-generation materials intended for diverse technological applications, such as CO 2 conversion, pollutant degradation, hydrogen generation, batteries, gas sensing, and solar cells. Finally, this review will open a new gateway for the synthesis of perovskite-based quantum dots.

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  • The use of lead-free materials raises challenges in achieving long-term stability under harsh environmental conditions, which is critical for many sensor applications.

    “Furthermore, the use of lead-free materials also raises challenges in achieving long-term stability under harsh environmental conditions, which is critical for many sensor applications [131,132].”

    From Design Strategies and Emerging Applications of Perovskite-Based Sensors (2025) · cites this paper as [132]

    “Understanding Lead-Free Halide Perovskites” (page unavailable) identifies stability as a challenge for lead-free materials. “Investigating Halide Perovskites” and “Gas Sensing” (pages unavailable) discuss degradation under moisture or heat and stability challenges for sensors, but do not specifically establish long-term stability under harsh conditions as a challenge for lead-free sensor materials. (LLM, conf=0.84)

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Research works printed but not linked: 204

  1. 10.1016/j.mssp.2023.107534 · DOI
  2. 10.1007/s10876-022-02317-3 · DOI
  3. 10.1016/j.snb.2022.131397 · DOI
  4. 10.1080/01614940.2024.2347479 · DOI
  5. 10.1557/s43578-023-01034-5 · DOI
  6. 10.1016/j.solener.2023.05.032 · DOI
  7. 10.1016/j.snb.2020.128751 · DOI
  8. 10.1016/j.nanoen.2023.108433 · DOI
  9. 10.1016/j.nanoen.2023.108297 · DOI
  10. 10.1016/j.jallcom.2022.167322 · DOI
  11. 10.1016/j.cej.2022.141248 · DOI
  12. 10.1002/kin.21389 · DOI
  13. 10.3390/molecules28227674 · DOI
  14. 10.1039/D1TA07733C · DOI
  15. 10.1016/j.cej.2021.132462 · DOI
  16. 10.1021/acs.langmuir.2c03310 · DOI
  17. 10.1016/j.cej.2021.131121 · DOI
  18. 10.1016/j.ijhydene.2023.06.315 · DOI
  19. 10.1016/j.jece.2020.104556 · DOI
  20. 10.1039/C9CY00127A · DOI
  21. 10.1016/j.matchemphys.2022.126581 · DOI
  22. 10.1016/j.ceramint.2023.03.227 · DOI
  23. 10.1016/j.ijhydene.2023.05.079 · DOI
  24. 10.1021/acsanm.4c00896 · DOI
  25. 10.3390/w16060848 · DOI
  26. 10.1016/j.jiec.2020.09.001 · DOI
  27. 10.1016/j.jeurceramsoc.2013.03.026 · DOI
  28. 10.1016/j.seppur.2022.121891 · DOI
  29. 10.1016/j.solener.2020.12.042 · DOI
  30. 10.1016/j.seppur.2022.122135 · DOI
  31. 10.1002/anie.202201300 · DOI
  32. 10.1038/s41586-021-04372-8 · DOI
  33. 10.1016/j.materresbull.2020.110857 · DOI
  34. 10.1016/j.cej.2021.134280 · DOI
  35. 10.1016/j.snb.2020.129076 · DOI
  36. 10.1016/j.ensm.2020.05.030 · DOI
  37. 10.1016/j.nanoen.2022.108148 · DOI
  38. 10.1016/j.optmat.2023.114004 · DOI
  39. 10.1016/j.ijhydene.2020.08.105 · DOI
  40. 10.1016/j.cej.2024.152024 · DOI
  41. 10.1039/D3EY00187C · DOI
  42. 10.1016/j.xcrp.2024.102020 · DOI
  43. 10.1063/5.0011851 · DOI
  44. 10.1021/acsomega.0c05092 · DOI
  45. 10.1107/S2052252523002208 · DOI
  46. 10.1103/PhysRevB.99.104105 · DOI
  47. 10.1016/j.cclet.2023.108707 · DOI
  48. 10.1021/acs.chemmater.9b05321 · DOI
  49. 10.1021/acsmaterialslett.1c00785 · DOI
  50. 10.1016/S1872-2067(19)63459-5 · DOI
  51. 10.1038/s41467-019-13856-1 · DOI
  52. 10.1016/j.mtchem.2023.101477 · DOI
  53. 10.1126/science.abb8985 · DOI
  54. 10.1038/s41586-019-1868-x · DOI
  55. 10.1016/j.seppur.2020.117526 · DOI
  56. 10.1016/j.jece.2023.109960 · DOI
  57. 10.1016/j.apsusc.2022.153276 · DOI
  58. 10.1021/acsomega.3c07606 · DOI
  59. 10.1016/j.apmt.2021.101307 · DOI
  60. 10.1016/j.snb.2022.132121 · DOI
  61. 10.1039/D2CC06408A · DOI
  62. 10.1016/j.snb.2022.133240 · DOI
  63. 10.1021/jacsau.1c00429 · DOI
  64. 10.1002/adma.202001344 · DOI
  65. 10.1021/acs.iecr.1c03810 · DOI
  66. 10.1016/j.matlet.2021.130874 · DOI
  67. 10.1016/j.nanoen.2019.104224 · DOI
  68. 10.1016/j.cej.2023.141473 · DOI
  69. 10.1016/j.cej.2023.144319 · DOI
  70. 10.1016/j.rser.2024.114615 · DOI
  71. 10.1016/j.apcatb.2023.123024 · DOI
  72. 10.1016/j.jallcom.2023.171509 · DOI
  73. 10.1016/j.jcis.2021.03.144 · DOI
  74. 10.1016/j.mtener.2021.100647 · DOI
  75. 10.1016/j.sna.2019.03.031 · DOI
  76. 10.1016/j.matpr.2023.05.677 · DOI
  77. 10.1016/j.comptc.2022.113624 · DOI
  78. 10.1016/j.nanoen.2021.106495 · DOI
  79. 10.1016/j.nanoen.2023.108273 · DOI
  80. 10.1016/j.scib.2024.01.027 · DOI
  81. 10.1016/j.apsusc.2023.158468 · DOI
  82. 10.1021/acs.jpclett.7b00105 · DOI
  83. 10.1016/j.ssc.2024.115537 · DOI
  84. 10.1016/j.apsusc.2023.159084 · DOI
  85. 10.1016/j.cej.2022.139909 · DOI
  86. 10.1016/j.cej.2020.126740 · DOI
  87. 10.1016/j.matdes.2019.108246 · DOI
  88. 10.1016/j.jip.2024.108072 · DOI
  89. 10.1016/j.optmat.2022.113398 · DOI
  90. 10.1016/j.jelechem.2020.114181 · DOI
  91. 10.1016/j.cej.2024.151099 · DOI
  92. 10.1016/j.apmt.2022.101658 · DOI
  93. 10.1016/j.nanoen.2022.107298 · DOI
  94. 10.1016/j.cej.2022.140331 · DOI
  95. 10.1016/j.jcis.2023.07.174 · DOI
  96. 10.1016/j.jtice.2024.105408 · DOI
  97. 10.1016/j.mtphys.2021.100358 · DOI
  98. 10.1039/D2CY00799A · DOI
  99. 10.1016/j.jmst.2022.12.057 · DOI
  100. 10.1016/j.ijhydene.2024.04.241 · DOI
  101. 10.1016/j.apcatb.2023.122881 · DOI
  102. 10.1016/j.cej.2023.143560 · DOI
  103. 10.1016/j.jmst.2020.06.047 · DOI
  104. 10.1016/j.jallcom.2024.173616 · DOI
  105. 10.1016/j.ceramint.2022.08.153 · DOI
  106. 10.1016/j.heliyon.2024.e27378 · DOI
  107. 10.1002/adma.202205303 · DOI
  108. 10.1002/anie.202116282 · DOI
  109. 10.1016/j.heliyon.2024.e25521 · DOI
  110. 10.1039/D0QI00496K · DOI
  111. 10.1016/j.jcis.2023.07.034 · DOI
  112. 10.1016/j.seppur.2023.123562 · DOI
  113. 10.1016/j.efmat.2023.01.002 · DOI
  114. 10.1016/j.mssp.2023.107707 · DOI
  115. 10.1016/j.biomaterials.2020.119773 · DOI
  116. 10.1039/D0NR02551H · DOI
  117. 10.1016/j.jclepro.2022.131367 · DOI
  118. 10.1016/j.apcatb.2021.120411 · DOI
  119. 10.1002/app.48513 · DOI
  120. 10.1016/j.seppur.2023.123526 · DOI
  121. 10.1002/adma.202270109 · DOI
  122. 10.1016/j.jpcs.2023.111747 · DOI
  123. 10.3389/fenvs.2023.1158399 · DOI
  124. 10.1016/j.cej.2024.151982 · DOI
  125. 10.1016/j.mtchem.2022.101357 · DOI
  126. 10.1016/j.jscs.2023.101753 · DOI
  127. 10.1016/j.matchemphys.2019.01.032 · DOI
  128. 10.1021/acs.chemmater.1c04051 · DOI
  129. 10.1016/j.jhazmat.2020.122793 · DOI
  130. 10.1016/j.jece.2023.109763 · DOI
  131. 10.1016/j.jmst.2023.08.053 · DOI
  132. 10.1016/j.mssp.2023.108019 · DOI
  133. 10.1016/j.dci.2023.104667 · DOI
  134. 10.1021/acsnano.1c07178 · DOI
  135. 10.1016/j.jcis.2023.02.012 · DOI
  136. 10.1016/j.jcis.2023.07.096 · DOI
  137. 10.1016/j.cej.2018.09.149 · DOI
  138. 10.1016/j.jssc.2019.121062 · DOI
  139. 10.1039/C9SC03829A · DOI
  140. 10.1021/jacs.1c05907 · DOI
  141. 10.3390/nano9081147 · DOI
  142. 10.1039/D1QM01006A · DOI
  143. 10.1016/j.foodchem.2022.135325 · DOI
  144. 10.1021/acsanm.1c00840 · DOI
  145. 10.1002/admi.202202404 · DOI
  146. 10.1038/s41467-023-36918-x · DOI
  147. 10.1016/j.cej.2022.140285 · DOI
  148. 10.1039/D3TC00430A · DOI
  149. 10.1021/acs.analchem.2c01702 · DOI
  150. 10.1088/1361-6528/acc1ec · DOI
  151. 10.1016/j.jcis.2021.11.045 · DOI
  152. 10.1002/anie.201904537 · DOI
  153. 10.1021/acs.inorgchem.9b03183 · DOI
  154. 10.1021/acsenergylett.8b01658 · DOI
  155. 10.1016/j.cej.2022.137102 · DOI
  156. 10.1039/D1TA00201E · DOI
  157. 10.1021/acs.inorgchem.8b00355 · DOI
  158. 10.1016/j.matchemphys.2022.127093 · DOI
  159. 10.1021/acs.jpcc.3c02341 · DOI
  160. 10.1021/acsmaterialslett.0c00376 · DOI
  161. 10.1039/C9TA05977F · DOI
  162. 10.1021/acsaem.2c00615 · DOI
  163. 10.1016/j.ijhydene.2022.09.174 · DOI
  164. 10.1039/D0NR04741D · DOI
  165. 10.1021/acsomega.9b03507 · DOI
  166. 10.1021/jacs.1c05907 · DOI
  167. 10.1016/j.cej.2019.123622 · DOI
  168. 10.1016/j.jcis.2019.07.054 · DOI
  169. 10.1021/acsami.2c13610 · DOI
  170. 10.1016/j.jallcom.2022.163946 · DOI
  171. 10.1038/s41467-023-37296-0 · DOI
  172. 10.1016/j.jphotochem.2023.114821 · DOI
  173. 10.1016/j.saa.2023.123091 · DOI
  174. 10.1002/adfm.202110030 · DOI
  175. 10.1039/D0TA02956D · DOI
  176. 10.1016/j.electacta.2019.135280 · DOI
  177. 10.1002/smll.202107161 · DOI
  178. 10.1016/j.surfin.2022.102358 · DOI
  179. 10.1021/acsanm.2c03067 · DOI
  180. 10.1016/j.cclet.2021.03.083 · DOI
  181. 10.1016/j.envres.2021.112650 · DOI
  182. 10.1039/D1CY01112J · DOI
  183. 10.1016/j.jallcom.2019.06.032 · DOI
  184. 10.1016/S1872-5813(12)60027-9 · DOI
  185. 10.3390/molecules24091779 · DOI
  186. 10.1016/j.cjche.2022.07.031 · DOI
  187. 10.1016/j.aej.2022.09.048 · DOI
  188. 10.1002/aoc.7122 · DOI
  189. 10.1002/jccs.202100276 · DOI
  190. 10.1038/s41598-024-52950-3 · DOI
  191. 10.1039/D2NJ03791B · DOI
  192. 10.1016/j.apcata.2021.118418 · DOI
  193. 10.1021/acsanm.8b02214 · DOI
  194. 10.1039/D1NJ05633F · DOI
  195. 10.1016/j.cattod.2019.03.044 · DOI
  196. 10.1515/ijcre-2020-0004 · DOI
  197. 10.3389/fchem.2020.00117 · DOI
  198. 10.1016/j.apcatb.2019.118313 · DOI
  199. 10.1007/s11426-014-5199-3 · DOI
  200. 10.3390/molecules27206976 · DOI

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Metadata

Authors
Altaf, A., Khan, I., Khan, A., Sadiq, S., Humayun, M., Khan, S., Zaman, S., Khan, A., Abumousa, R. A., & Bououdina, M.
Affiliations
  • Jiangsu University of Science and Technology (CN)
  • Prince Sultan University (SA)
  • Northeast Agricultural University (CN)
  • Liaoning University (CN)
Corresponding author
Khan, Iltaf
ORCID
Venue
ACS Omega
Publisher
American Chemical Society (ACS)
Published
2024-08-01
Volume
9
Issue
32
Pages
34220-34242
ISSN
2470-1343 (ISSN-L)
DOI
10.1021/acsomega.4c04532
PMC
PMC11325423
OpenAlex
W4401210089
Cited by
67
References
0
Citations by year
2026: 16 · 2025: 45 · 2024: 6
FWCI
1.52
Type
journal article
Language
en
Open access
Licence
Locations
  • ACS Omega (publishedVersion, cc-by-nc-nd)
  • PubMed Central (publishedVersion, cc-by-nc-nd)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
Jiangsu University of Science and Technology (1112932205)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Perovskite Materials and Applications
  • Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
  • Physical Sciences › Materials Science › Materials Chemistry › Quantum Dots Synthesis And Properties
Keywords
lead-free halide perovskites, halide perovskite quantum dots, metal-organic frameworks, covalent organic frameworks, hybrid nanocatalysts, perovskite stability, CO2 conversion, pollutant degradation, hydrogen production, batteries, gas sensing, solar cells, photoluminescence quantum yield, charge separation

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