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Cited by 52Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsAdvanced Photocatalysis Techniques

Catalytic Properties of Vanadium Diselenide: A Comprehensive Study on Its Electrocatalytic Performance in Alkaline, Neutral, and Acidic Media

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Ulusoy Ghobadi, T. Gamze, Patil, Bhushan, Karadas, Ferdi, Okyay, Ali K., Yilmaz, Eda·2017·ACS Omega
DOI 10.1021/acsomega.7b01226PMC PMC6645278
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Abstract

Here, we report the synthesis of vanadium diselenide (VSe2) three-dimensional nanoparticles (NPs) and two-dimensional (2D) nanosheets (NSs) utilizing nanosecond pulsed laser ablation technique followed by liquid-phase exfoliation. Furthermore, a systematic study has been conducted on the effect of NP and NS morphologies of VSe2 in their catalytic activities toward oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) under alkaline, neutral, and acidic conditions. Research on VSe2 clearly demonstrates that these morphologies do not have a significant difference for ORR and OER; however, a drastic effect of morphology was observed for HER. The ORR activity of both NSs and NPs involves ∼2.85 numbers of electrons with the Tafel slope of 120 mV/dec in alkaline and neutral pH. In alkaline solution, NPs are proved to be an efficient catalyst for OER with an onset potential 1.5 V; however, for HER, NSs have a better onset potential of −0.25 V. Moreover, the obtained NPs have also better catalytic activity with a 400 mV anodic shift in the onset potential compared to NSs. These results provide a reference point for the future application of VSe2 in energy storage and conversion devices and mass production of other 2D materials.

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Sorted by citations

Authors
Ulusoy Ghobadi, T. G., Patil, B., Karadas, F., Okyay, A. K., & Yilmaz, E.
Affiliations
  • Bilkent University , , , ,
  • Bilkent University (TR)
ORCID
Venue
ACS Omega
Publisher
American Chemical Society (ACS)
Published
2017-11-27
Volume
2
Issue
11
Pages
8319-8329
ISSN
2470-1343 (ISSN-L)
DOI
10.1021/acsomega.7b01226
PMC
PMC6645278
OpenAlex
W2768491582
Cited by
52
References
1
Citations by year
2026: 1 · 2025: 7 · 2024: 6 · 2023: 9 · 2022: 7 · 2021: 4 · 2020: 8 · 2019: 5 · 2018: 5
FWCI
1.32
Type
journal article
Language
en
Open access
Licence
Locations
  • ACS Omega (publishedVersion, other-oa)
  • PubMed Central (publishedVersion)
  • PubMed (publishedVersion)
  • Bilkent University Institutional Repository (Bilkent University) (submittedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
Türkiye Bilimsel ve Teknolojik Arastirma Kurumu (115M375)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
Keywords
VSe2, electrocatalysis, oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, nanosheets, nanoparticles, morphology effects, alkaline solution, acidic media, media neutrality, liquid-phase exfoliation, nanosecond laser ablation, two-dimensional materials

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