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Phosphorus- and Sulfur-Codoped g-C3N4: Facile Preparation, Mechanism Insight, and Application as Efficient Photocatalyst for Tetracycline and Methyl Orange Degradation under Visible Light Irradiation

Jiang, Longbo, Yuan, Xingzhong, Zeng, Guangming, Chen, Xiaohong, Wu, Zhibin, Liang, Jie, Zhang, Jin, Wang, Hui, Wang, Hou·2017·ACS Sustainable Chemistry & Engineering

Abstract

Phosphorus- and sulfur-codoped graphitic carbon nitride has been successfully synthesized by in situ thermal copolymerization of hexachlorocyclotriphosphazene and thiourea. The phosphorus doping, together with the sulfur doping, would enhance light trapping, surface area, and charge separation, making it serve as a more efficient photocatalyst than its pure g-C 3 N 4 and single-doped g-C 3 N 4 counterpart for the removal of tetracycline (TC) and methyl orange (MO). The optimum photocatalytic activities of a P-, S-codoped g-C 3 N 4 sample for the degradation of TC and MO were about 5.9 times and 7.1 times higher than that of individual g-C 3 N 4, respectively. Furthermore, the optimum TOC removal reached 70.33% and 55.37% for TC and MO within 120 min, respectively. The introduction of a P atom and S atom could significantly change the electronic property of g-C 3 N 4 and suppress the recombination of photogenerated charges. Moreover, the defects in the framework of samples caused by the doping of P and S could serve as centers to trap the photoinduced electrons, thus inhibiting the charge recombination and improving its photocatalytic performance.

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Metadata

Authors
Jiang, L., Yuan, X., Zeng, G., Chen, X., Wu, Z., Liang, J., Zhang, J., Wang, H., & Wang, H.
Venue
ACS Sustainable Chemistry & Engineering
Published
2017-06-14
Volume
5
Issue
7
Pages
5831-5841
ISSN
2168-0485 (ISSN-L)
OpenAlex
W2623193283
Cited by
422
References
56
FWCI
13.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Phosphorus- and Sulfur-Codoped g-C3N4: Facile Preparation, Mechanism Insight, and Application as Efficient Photocatalyst for Tetracycline and Methyl Orange Degradation under Visible Light Irradiation. https://app.cochat.ai/papers/10.1021/acssuschemeng.7b00559
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Jiang, L., Yuan, X., Zeng, G., Chen, X., Wu, Z., Liang, J., Zhang, J., Wang, H., & Wang, H. (2017). Phosphorus- and Sulfur-Codoped g-C3N4: Facile Preparation, Mechanism Insight, and Application as Efficient Photocatalyst for Tetracycline and Methyl Orange Degradation under Visible Light Irradiation. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.7b00559

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.